64486-90-4

Basic information

• Product Name: 1,3-di-tert-butyl-2-chloro-2,3-dihydro-1H-1,3,2-diazaborole
• Synonyms: 1,3-di-tert-butyl-2-chloro-2,3-dihydro-1H-1,3,2-diazaborole
• CAS NO: 64486-90-4
• Molecular Weight: 214.546
• Mol File: 64486-90-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-di-tert-butyl-2-chloro-2,3-dihydro-1H-1,3,2-diazaborole(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-di-tert-butyl-2-chloro-2,3-dihydro-1H-1,3,2-diazaborole(64486-90-4)
• EPA Substance Registry System: 1,3-di-tert-butyl-2-chloro-2,3-dihydro-1H-1,3,2-diazaborole(64486-90-4)

Safety Data

• Hazardous Substances Data: 64486-90-4(Hazardous Substances Data)

Relevant articles and documents

Preparation, Structure and Reactivity of 2-Chloro-, 2-Fluoro- and 2-Iodo-2,3-dihydro-1H-1,3,2-diazaboroles

A series of differently substituted 2-chloro-, 2-fluoro- and 2-iodo-2,3-dihydro-1H-1,3,2-diazaboroles have been prepared by various methods. 1,3-Di-tert-butyl-2-fruoro-2,3-dihydro1H-1,3,2-diazaborole (3a), 1,3-di-tert-butyl-2-chloro-2,3-dihydro-1H-1,3,2-diazaborole (5a), 1,3-bis(2,6-dimethyl-phenyl)-2-chloro-2,3-dihydro-1H-1,3,2-diazaborole (5b), 2-chloro-4,5-dimethyl-1,3-dineopentyl-2,3-dihydro-1H-1,3,2-diazaborole (Sc), and 1,3-di-tert-butyl-2-iodo-2,3-dihydro-1H-1,3,2-diazaborole (6a) were formed from the corresponding lithiated Z-1,2-diaminoethenes, by treatment with BF3·OEt2, BCl3, or BI3 in n-hexane. Compounds 3a, 5a, and 5b are also available by sodium amalgam reduction of the adduct (tBu)(BF3)N=CH-CH=N(BF3)(tBu) (2a), and the borolium salts [RNa=CH-CH=Nb(R)BCl2]X (Na-B) (4a: R = tBu, X = BCl4 and 4b: R = 2,6-Me2C6H2, X = Cl) respectively. The iodo derivative (2,6-Me2C6H2)-Na-CH=CH-N b(2,6-Me2C6H2)BI (Na-B) (6b) was synthesized in a redox reaction between the 1,4-diazabutadiene 1b and Bl3. The novel compounds were characterized by 1H-, 11B- and 13C-NMR spectroscopy, as well as by an X-ray structure analysis of 6b.