64494-03-7

Basic information

• Product Name: 1,2,4-Triazine, 3-(4-methoxyphenyl)-6-(2-thienyl)-
• CAS NO: 64494-03-7
• Molecular Formula: C14H11N3OS
• Molecular Weight: 269.327
• Mol File: 64494-03-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2,4-Triazine, 3-(4-methoxyphenyl)-6-(2-thienyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,4-Triazine, 3-(4-methoxyphenyl)-6-(2-thienyl)-(64494-03-7)
• EPA Substance Registry System: 1,2,4-Triazine, 3-(4-methoxyphenyl)-6-(2-thienyl)-(64494-03-7)

Safety Data

• Hazardous Substances Data: 64494-03-7(Hazardous Substances Data)

Upstream product

• 10531-41-6 2-Bromoacetylthiophene 
• 3290-99-1 4-methoxybenzoic acid hydrazide 

Relevant articles and documents

Tuning the Excimer Emission of Amphiphilic Platinum(II) Complexes Mediated by Phospholipid Vesicles

Two new amphiphilic platinum(II) complexes, [Pt(2-(4-fluorophenyl)-5-(4-dodecyloxyphenyl)pyridine) (acac)] (Pt-1) and [Pt(2-(4-dodecyloxyphenyl)-5-(thien-2-yl)-c-cyclopentenepyridine) (acac)] (Pt-2), where acac is acetylacetonate, were synthesized and characterized. Apart from conventional phosphorescence of single molecules (ME-monomer emission), complexes Pt-1 and Pt-2 also exhibit excimer emission (EE) when embedded into phospholipid vesicles, that is assigned to emissive Pt-Pt excimers. The EE intensity in vesicular media appeared to depend on the viscosity of the vesicles and the concentration of the embedded complex. Differences in the EE properties of complexes Pt-1 and Pt-2 are correlated with the energies of the π-character frontier orbitals defined by the design of the cyclometalating phenylpyridine ligand. Higher energies of the frontier π-orbitals (HOMO and LUMO) naturally promote stronger π-π interactions, thus obstructing the PtII-PtII interaction.