64520-63-4Relevant articles and documents
Regioselective Synthesis of Difluorinated C-Furanosides Involving a Debenzylative Cycloetherification
Delbrouck, Julien A.,Bochatay, Valentin N.,Tikad, Abdellatif,Vincent, Stéphane P.
, p. 5562 - 5566 (2019/08/01)
A highly regioselective synthesis of valuable gem-difluorinated C-furanosides from unprotected aldoses via a debenzylative cycloetherification (DBCE) reaction induced by diethylaminosulfur trifluoride is descibed. The scope and limitations of this DBCE reaction are described using a series of commercially available pentoses and hexoses to afford, without selective protection/deprotection sequences, the corresponding gem-difluorinated C-furanosides in moderate to good yields.
N-Monoalkylation of Tetra-O-benzyl-D-arabinonamide: Synthesis of Some Open-Chain Analogues of N-Acetylneuraminic Acid and Their Evaluation as Sialidase Inhibitors
Storz, Thomas,Vasella, Andrea
, p. 1896 - 1907 (2007/10/03)
N-Arabinonoylglycine 2, its phospho analogue (arabinonoylamino)methylphosphonate 14, N-arabinonoyltaurine salt 18, and [2-(arabinonoylamino)ethylidene]bis[phosphonic acid] 22 have been synthesized from D-arabinose in seven (2 or 14), and eight steps (18 o