6462-34-6

Basic information

• Product Name: 4-METHANESULFONYL-BIPHENYL
• Synonyms: 4-METHANESULFONYL-BIPHENYL
• CAS NO: 6462-34-6
• Molecular Formula: C13H12O2S
• Molecular Weight: 232.29818
• Mol File: 6462-34-6.mol
• Article Data: 29

Chemical Properties

• Boiling Point: 415.7°C at 760 mmHg
• Flash Point: 257.4°C
• Appearance: /
• Density: 1.182g/cm³
• Vapor Pressure: 9.77E-07mmHg at 25°C
• Refractive Index: 1.574
• CAS DataBase Reference: 4-METHANESULFONYL-BIPHENYL(CAS DataBase Reference)
• NIST Chemistry Reference: 4-METHANESULFONYL-BIPHENYL(6462-34-6)
• EPA Substance Registry System: 4-METHANESULFONYL-BIPHENYL(6462-34-6)

Safety Data

• Hazardous Substances Data: 6462-34-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H12O2S/c1-16(14,15)13-9-7-12(8-10-13)11-5-3-2-4-6-11/h2-10H,1H3

Upstream product

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• 67-68-5 dimethyl sulfoxide 

Relevant articles and documents

Pd–Ni bimetallic catalyst supported on dendrimer-functionalized magnetic graphene oxide for efficient catalytic Suzuki-Miyaura coupling reaction

A novel type of dendritic structure was grown on the magnetic graphene oxide nanocomposite surface through thiol-ene click reaction. The resulting nanocomposite was utilized as a support for immobilizing Pd–Ni bimetallic nanoparticles, which were employed

Sustainable and recyclable magnetic nanocatalyst of 1,10-phenanthroline Pd(0) complex in green synthesis of biaryls and tetrazoles using arylboronic acids as versatile substrates

A magnetic nanocatalyst was purveyed as a heterogeneous recoverable palladium-based catalyst anchored on green, sustainable and phosphine free support. Resulted Fe3O4@SiO2-Phen-Pd(0) nanocatalyst bearing powerful phenanthroline ligand was thoroughly characterized by physicochemical approaches like UV–vis, FT-IR, EDX, XRD, TGA, ICP, VSM, DLS, FESEM, and TEM analyses. After finding trustable data, the obtained magnetic catalyst was considered to be applied in the Suzuki-Miyaura type C-C couplings and getting corresponding tetrazoles using arylboronic acid derivatives as alternate precursors of aromatic halides and stupendous data were observed.

Preparation method of methyl sulfone compound

The invention discloses a synthesis method of a methyl sulfone compound, which comprises the following steps: by using an iodinated compound as a substrate, adding a sulfite compound into the substrate, and using a 1, 4-dioxane solution as a solvent, heating under the protection of nitrogen under the actions of a silicon reagent, a phase transfer catalyst and a palladium catalyst to obtain a crudeproduct; then purifying the crude product, firstly filtering the crude product, and removing the solvent to obtain residues; carrying out silica gel column chromatography on the residues, leaching with eluent, and collecting effluent; combining the effluent containing the product; and concentrating the combined effluent to remove the solvent, and finally carrying out vacuum drying to obtain the target product. The method has the advantages of simple process flow, easiness in product purification, environmental safety and high yield.