646535-49-1Relevant articles and documents
β-Diiminate Platinum Complexes for Alkane Dehydrogenation
Fekl, Ulrich,Kaminsky, Werner,Goldberg, Karen I.
, p. 15286 - 15287 (2007/10/03)
New five-coordinate Pt(IV) complexes [{(o-R2-p-R′-C6H2)NC(R″)}2CH]PtMe3 (R, R′, R″ = alkyl or H) are reported. The complex with R = Me, R′ = tBu, R″ = Me generates unsaturated Pt(II) species capable of alkane C?H bond activation and stoichiometric dehydrogenation. Copyright