6471-66-5

Basic information

• Product Name: benzyl nonan-1-oate
• Synonyms: Pelargonic acid benzyl ester;Einecs 229-316-9;Nonanoic acid, phenylmethyl ester;benzyl nonan-1-oate;Nonanoic acid benzyl ester;BENZYL NONANOATE
• CAS NO: 6471-66-5
• Molecular Formula: C₁₆H₂₄O₂
• Molecular Weight: 248.36056
• EINECS: 229-316-9
• Mol File: 6471-66-5.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 328.7°C at 760 mmHg
• Flash Point: 109.1°C
• Appearance: /
• Density: 0.963g/cm³
• Vapor Pressure: 0.000186mmHg at 25°C
• Refractive Index: 1.49
• CAS DataBase Reference: benzyl nonan-1-oate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl nonan-1-oate(6471-66-5)
• EPA Substance Registry System: benzyl nonan-1-oate(6471-66-5)

Safety Data

• Hazardous Substances Data: 6471-66-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H24O2/c1-2-3-4-5-6-10-13-16(17)18-14-15-11-8-7-9-12-15/h7-9,11-12H,2-6,10,13-14H2,1H3

Upstream product

• 112-05-0 nonanoic acid 
• 28867-76-7 benzaldehyde benzylidenehydrazone 
• 100-39-0 benzyl bromide 
• 1731-84-6 nonanoic acid methyl ester 
• 100-51-6 benzyl alcohol 
• 100-52-7 benzaldehyde 
• 111-66-0 oct-1-ene 
• 104-57-4 benzyl formate 
• 111-67-1 2-octene 
• 201230-82-2 carbon monoxide 
• 13389-42-9 trans-2-Octene 
• 111-65-9 octane 
• 2495-35-4 benzylacrylate 
• 638-45-9 1-Iodohexane 

Relevant articles and documents

Visible-light-initiated manganese-catalyzed Giese addition of unactivated alkyl iodides to electron-poor olefins

Herein, we report a mild protocol for direct visible-light-initiated Giese addition of unactivated alkyl iodides to electron-poor olefins (Michael acceptors) with catalysis by decacarbonyl dimanganese, Mn2(CO)10, an inexpensive earth-abundant-metal catalyst. This protocol is compatible with a wide array of sensitive functional groups and has a broad substrate scope with regard to both the alkyl iodide and the Michael acceptor.

The scope and mechanism of palladium-catalysed Markovnikov alkoxycarbonylation of alkenes

Hydroesterification reactions represent a fundamental type of carbonylation reaction and constitute one of the most important industrial applications of homogeneous catalysis. Over the past 70 years, numerous catalyst systems have been developed that allow for highly linear-selective (anti-Markovnikov) reactions and are used in industry to produce linear carboxylates starting from olefins. In contrast, a general catalyst system for Markovnikov-selective alkoxycarbonylation of aliphatic olefins remains unknown. In this paper, we show that a specific palladium catalyst system consisting of PdX2/N-phenylpyrrole phosphine (X, halide) catalyses the alkoxycarbonylation of various alkenes to give the branched esters in high selectivity (branched selectivity up to 91%). The observed (and unexpected) selectivity has been rationalized by density functional theory computation that includes a dispersion correction.

Novel ruthenium-catalyst for hydroesterification of olefins with formates

An alternative ruthenium-based catalyst for the hydroesterification of olefins with formates is reported. The good activity of our system is ensured by the use of a bidentate P,N-ligand and ruthenium dodecacarbonyl. A range of formates can be used for selective alkoxycarbonylation of aromatic olefins. In addition, the synthesis of selected aliphatic esters is realized. The proposed active ruthenium complex has been isolated and characterized. This journal is the Partner Organisations 2014.