6476-60-4Relevant articles and documents
A new precursor for the synthesis of porphyrazine: 2,3-bis(4-methyl-phenyl)maleonitrile
Faulmann, Christophe,Cassoux, Patrick,Pullen, Anthony E.
, p. 384 - 385 (2000)
The structure of the title compound consists of discrete C18H14N2 molecules in a cis configuration. The molecules are distorted from planarity.
Enediynes from aza-enediynes: C,N-dialkynyl imines undergo both aza-Bergman rearrangement and conversion to enediynes and fumaronitriles
Feng, Liping,Zhang, Aibin,Kerwin, Sean M.
, p. 1983 - 1986 (2007/10/03)
Aza-enediynes (C,N-dialkynyl imines) undergo thermal aza-Bergman rearrangement to β-alkynyl acrylonitriles through 2,5-didehydropyridine (2,5-ddp) intermediates. Certain aza-enediynes also undergo an alternative process affording enediynes and fumaronitri
Application of Cyanophosphates in Organic Synthesis. Reactivity of α-Cyano-α-diethylphosphonooxy Anions
Kurihara, Takushi,Santo, Kazunori,Harusawa, Shinya,Yoneda, Ryuji
, p. 4777 - 4788 (2007/10/02)
The utility of the cyanohydrin diethylphosphates derived from aldehydes (arylaldehydes,crotonaldehyde, and cinnamaldehyde) as an acyl anion equivalent was examined.Deprotonation of cyanophosphates with n-butyllithium in the presence of tetramethylethylene