64768-18-9

Basic information

• Product Name: p-nitrophenyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside
• Synonyms: p-nitrophenyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside
• CAS NO: 64768-18-9
• Molecular Weight: 717.686
• Mol File: 64768-18-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: p-nitrophenyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: p-nitrophenyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside(64768-18-9)
• EPA Substance Registry System: p-nitrophenyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside(64768-18-9)

Safety Data

• Hazardous Substances Data: 64768-18-9(Hazardous Substances Data)

Upstream product

• 24067-17-2 4-nitrophenylboronic acid 
• 627466-84-6 2,3,4,6-tetra-O-benzoyl-D-galactose 
• 25878-60-8 D-galactose pentaacetate 
• 100-02-7 4-nitro-phenol 
• 17042-39-6 p-nitrophenyl 2,3,4,6-tetra-O-acetyl-α-D-galactopyranoside 
• 100-44-7 benzyl chloride 
• 7493-95-0 4-nitrophenyl α-D-galactoside 
• 627466-64-2 2,3,4,6-tetra-O-benzoyl-D-glucopyranose 
• 98-88-4 benzoyl chloride 
• 2492-87-7 4-nitrophenyl-β-D-glucoside 
• 572-10-1 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl chloride 

Downstream Products

• 80245-21-2 p-nitrophenyl 3,4,6-tri-O-benzoyl-β-D-glucopyranoside 

Relevant articles and documents

Copper-mediated O-arylation of lactols with aryl boronic acids

An efficient and novel methodology to access phenolic glycosides has been established by using copper-mediated coupling reaction of aryl boronic acids with hemiacetals. The reaction takes place normally in the presence of Cu(OAc)2 (1.0 equiv.) and pyridine (2.0 equiv.) at 40 °C. This protocol distinguishes itself by wide substrate scope, operational simplicity and giving rise to a myriad of phenolic glycosides in good to excellent yields.

REGIOSELECTIVE O-DEACYLATION OF FULLY ACYLATED GLYCOSIDES AND 1,2-O-ISOPORPYLIDENEALDOFURANOSE DERIVATIVES WITH HYDRAZINE HYDRATE

On hydrazinolyis in 1:4 acetic acid-pyridine, and in pyridine, partisl O-deacylation of fully acylated methyl glycosides and some other glycosyl compounds ( 23 compounds ) was found to be induced, to give, in good yields, products bearing one free hydroxy