64836-82-4

Basic information

• Product Name: Diethyl4-oxocyclohex-2-ene-1,1-dicarboxylate
• Synonyms: Diethyl4-oxocyclohex-2-ene-1,1-dicarboxylate
• CAS NO: 64836-82-4
• Molecular Formula: C₁₂H₁₆O₅
• Molecular Weight: 240.25244
• Mol File: 64836-82-4.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: Diethyl4-oxocyclohex-2-ene-1,1-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: Diethyl4-oxocyclohex-2-ene-1,1-dicarboxylate(64836-82-4)
• EPA Substance Registry System: Diethyl4-oxocyclohex-2-ene-1,1-dicarboxylate(64836-82-4)

Safety Data

• Hazardous Substances Data: 64836-82-4(Hazardous Substances Data)

Usage

General Description

Diethyl 4-oxocyclohex-2-ene-1,1-dicarboxylate is a chemical compound with the molecular formula C14H20O5. It is commonly used as a building block in organic synthesis and chemical reactions, particularly in the pharmaceutical industry for the synthesis of various drugs. Diethyl4-oxocyclohex-2-ene-1,1-dicarboxylate is a derivative of cyclohex-2-ene-1,1-dicarboxylic acid, with two ethyl ester groups attached to the cyclohexene ring. It is known for its potential use as a ligand in coordination chemistry and for its ability to undergo various chemical transformations, making it a valuable component in the production of organic compounds with diverse applications. Additionally, it has demonstrated potential biological activity, which may be of interest for further research and development in pharmaceuticals and other fields.

Upstream product

• 3377-20-6 diethyl methylenemalonate 
• 59414-23-2 1-methoxy-3-<(trimethylsilyl)oxy>01,3-butadiene 

Downstream Products

• 64836-83-5 4-Oxo-cyclohexa-2,5-diene-1,1-dicarboxylic acid diethyl ester 

Relevant articles and documents

Synthesis of cobalt-substituted 1,3-diene complexes with unusual structures and their exo-selective Diels-Alder reactions

The synthesis and characterization (including crystallographic data) of several substituted-pyridine (Rpyr) cobalt bis(dimethylglyoxime) 1,3-butadiene complexes (R = H, tBu, 3,5-diMe, and N,N-dimethylamino) and their Diels-Alder reactions with a variety of dienophiles are reported here. The cobalt-carbon bonds in the Diels-Alder cycloadducts can be cleaved so that cobalt complexes as well as functionalized organic cycloadducts are recovered. Through these cobalt-carbon bond cleavage reactions, cobalt-diene complexes can serve as synthons for a variety of 1,3-dienes such as 1,3-butadiene, 2-(trimethylsiloxy)- 1,3-butadiene, iodoprene, (E)-1-methoxy-3-(trimethylsiloxy)-1,3-butadiene (Danishefsky's diene), and 1,2-dichloro-1,3-butadiene. The preparation of several cobalt-substituted 1,2- and 1,3-pentadiene complexes and highly exo-selective Diels-Alder reactions of the 1,3-pentadiene complexes are then discussed followed by demetalation reactions of these more highly substituted cobalt cycloadducts. These demetalation reactions maintain the stereochemical integrity found in the metal cycloadducts and also lead to cobalt recovery.