6493-80-7

Basic information

• Product Name: methyl 1-methylcyclohex-3-ene-1-carboxylate
• Synonyms: methyl 1-methylcyclohex-3-ene-1-carboxylate;3-Cyclohexene-1-carboxylic acid, 1-methyl-, methyl ester;METHYL1-METHYLCYCLOHEX-3-ENECARBOXYLATE;Methyl-1-methylcyclohex-3-en-1-carboxylat;Tachrysate;1-Methyl-3-cyclohexene-1-carboxylic acid methyl ester;tagette carboxylate
• CAS NO: 6493-80-7
• Molecular Formula: C₉H₁₄O₂
• Molecular Weight: 154.20626
• EINECS: 229-377-1
• Mol File: 6493-80-7.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 183.2°Cat760mmHg
• Flash Point: 54.7°C
• Appearance: /
• Density: 0.989g/cm³
• Vapor Pressure: 0.778mmHg at 25°C
• Refractive Index: 1.462
• CAS DataBase Reference: methyl 1-methylcyclohex-3-ene-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 1-methylcyclohex-3-ene-1-carboxylate(6493-80-7)
• EPA Substance Registry System: methyl 1-methylcyclohex-3-ene-1-carboxylate(6493-80-7)

Safety Data

• Hazardous Substances Data: 6493-80-7(Hazardous Substances Data)

Usage

General Description

Methyl 1-methylcyclohex-3-ene-1-carboxylate is a chemical compound with the molecular formula C9H14O2. It is an ester, specifically a methyl ester, of 1-methylcyclohex-3-ene-1-carboxylic acid. methyl 1-methylcyclohex-3-ene-1-carboxylate is commonly used as a flavoring agent in the food and beverage industry, adding a fruity and sweet aroma to products. It is also used in the production of perfumes and fragrances. Additionally, it can be used as a solvent in the production of various organic compounds. Methyl 1-methylcyclohex-3-ene-1-carboxylate is flammable and should be handled and stored with care.

InChI:InChI=1/C9H14O2/c1-9(8(10)11-2)6-4-3-5-7-9/h3-4H,5-7H2,1-2H3

Upstream product

• 106-99-0 buta-1,3-diene 
• 80-62-6 methacrylic acid methyl ester 
• 6493-77-2 methyl cyclohex-3-ene-1-carboxylate 
• 74-88-4 methyl iodide 

Downstream Products

• 825-04-7 methyl 1-methylcyclohexanecarboxylate 
• 50552-10-8 1-Hydroxymethyl-1-methyl-cyclohex-3-en 
• 76657-91-5 trans-1-Hydroxy-4-methyl-4-cyclohexancarbonsaeure 
• 87787-02-8 (1α,4β)-1-methyl-4-hydroxycyclohexanecarboxylic acid methyl ester 
• 56294-21-4 methyl 1-methyl-3-oxo-4-cyclohexenecarboxylate 
• 16646-42-7 1-methyl-3-cyclohexenecarboxylic acid 
• 56294-19-0 methyl 1-methyl-3-oxocyclohexane-1-carboxylate 
• 87873-09-4 4-(7-Methyl-1,4-dioxa-spiro[4.5]dec-7-ylmethoxy)-phenylamine 
• 87787-15-3 4-(3,3-ethylenedioxy-1-methylcyclohexylmethoxy)nitrobenzene 
• 87787-12-0 1-methyl-t-4-(2-tetrahydropyranyloxy)-r-1-cyclohexanemethanol 
• 87787-24-4 4-(4-Amino-phenoxymethyl)-4-methyl-cyclohexanol 
• 93392-64-4 1-Methyl-4-(tetrahydro-pyran-2-yloxy)-cyclohexanecarboxylic acid methyl ester 
• 93392-67-7 4-(t-4-hydroxy-1-methyl-r-1-cyclohexylmethoxy)nitrobenzene 
• 93392-62-2 methyl 2-bromo-3-<4-(t-4-hydroxy-1-methyl-r-1-cyclohexylmethoxy)phenyl>propionate 

Relevant articles and documents

New entry to the enantioselective formation of substituted cyclohexenes bearing an all-carbon quaternary stereogenic center

Enantioselective formation of cyclohexene derivatives bearing an all-carbon quaternary stereogenic center is described. The racemic cyclohexenes are readily transformed to chiral substituted cyclohexenes in good yield with excellent enantioselectivity and diastereoselectivity by a palladium-mediated deracemization. The resulting products are promising synthetic intermediates of biologically active natural products. This protocol provides us with a new entry to the concise and scalable synthesis of multifunctionalized compounds.

Enones with Strained Double Bonds. 8. The Bicyclooctane Systems

The bicyclic enones bicyclooct-1-en-3-one (4) and 1-methylbicyclooct-5(6)-en-7-one (5) have been generated from various precursors and trapped by the addition of nucleophiles such as MeOH, PhSeH, or H2O.The bridgehead enone 5 has also been trapped as its cycloadduct 31 with furan.Pyrolysis of this cycloadduct 31 reformed the bridgehead enone 5 that was trapped as the cycloadduct 32.Related bridgehead enones 35 and 47 have also been generated as intermediates leading to products with bridgehead methoxy substituents.