6500-63-6Relevant articles and documents
The total synthesis of hypodematine
Kang, Zhi-Yun,Zhang, Qing-Jian,Chen, Ruo-Yun,Zhang, Pei-Cheng,Yu, De-Quan
, p. 840 - 848 (2013/09/23)
Hypodematine, isolated from Hypodematium sinense Iwatsuki as an alkaloid with a new skeleton, was synthesized via nine reaction steps, in which the synthesis of 2-aryl-1-benzazocines via Beckmann rearrangement of 5H-benzocyclohepten-5-one oxime mesylate i
Studies in Antifertility Agents: Part XXXIII- Synthesis of 1,2-trans-1--2-benzyl-7-methoxybenzosuberan
Sangwan, Naresh K.,Rastogi, Shri Nivas
, p. 140 - 143 (2007/10/02)
Condensation of 7-methoxy-1-benzosuberone (4) with PhCHO gives 2-benzylidene derivative (5) which on hydrogenation over Pd-C affords the corresponding 2-benzyl analog (6).Reduction of 6 with KBH4 furnishes a mixture of 1,2-cis- and trans-2-benzyl-1-benzos