65036-52-4

Basic information

• Product Name: 6-methoxy-2-nitrobenzenediazonium chloride
• Synonyms: 6-methoxy-2-nitrobenzenediazonium chloride
• CAS NO: 65036-52-4
• Molecular Weight: 215.596
• Mol File: 65036-52-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-methoxy-2-nitrobenzenediazonium chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 6-methoxy-2-nitrobenzenediazonium chloride(65036-52-4)
• EPA Substance Registry System: 6-methoxy-2-nitrobenzenediazonium chloride(65036-52-4)

Safety Data

• Hazardous Substances Data: 65036-52-4(Hazardous Substances Data)

Upstream product

• 16554-45-3 2-methoxy-6-nitroaniline 

Downstream Products

• 85355-48-2 (2-Methoxy-6-nitro-phenyl)-acetaldehyde 
• 85355-37-9 Acetic acid 1-chloro-2-(2-methoxy-6-nitro-phenyl)-ethyl ester 
• 4837-90-5 4-methoxy-1H-indole 

Relevant articles and documents

Synthesis of Substituted Indoles via Meerwein Arylation

A new method for the synthesis of substituted indoles is detailed.Meerwein arylation of 4- and 6-substituted 2-nitrobenzenediazonium chlorides with vinyl acetate or vinyl bromide and subsequent reductive cyclization of the resulting adducts affords the corresponding 6- and 4-substituted (CH3, OCH3, Cl, Br, CF3) indoles.The diazonium bisulfates of weakly basic 2-nitroanilines (4-Cl, 6-Br, 4-CF3) gave higher yields of Meerwein arylation adducts than the corresponding diazonium chlorides.Coupling of 2-nitrobenzenediazonium chloride with 2-acetoxy-1-alkenes followed byreductive cyclization affords 2-alkylindoles.