65200-70-6

Basic information

• Product Name: Ethanone, 2-(2-methoxyphenyl)-1-(4-methoxyphenyl)-
• CAS NO: 65200-70-6
• Molecular Formula: C16H16O3
• Molecular Weight: 256.301
• Mol File: 65200-70-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-(2-methoxyphenyl)-1-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-(2-methoxyphenyl)-1-(4-methoxyphenyl)-(65200-70-6)
• EPA Substance Registry System: Ethanone, 2-(2-methoxyphenyl)-1-(4-methoxyphenyl)-(65200-70-6)

Safety Data

• Hazardous Substances Data: 65200-70-6(Hazardous Substances Data)

Upstream product

• 100-66-3 methoxybenzene 
• 28033-63-8 2-(2-methoxyphenyl)acetyl chloride 
• 766-51-8 2-Chloroanisole 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 1548157-96-5 C₁₇H₁₆O₄ 
• 1542580-99-3 C₁₇H₁₆O₄ 
• 3319-15-1 rac-1-(4-methoxyphenyl)-ethanol 
• 5449-69-4 2,4'-dimethoxybenzophenone 
• 3343-80-4 (2-ethylbenzofuran-3-yl)(4-methoxyphenyl)methanone 
• 74-88-4 methyl iodide 
• 24890-61-7 1-methoxy-2-(1-(4-methoxyphenyl)vinyl)benzene 

Downstream Products

• 108840-09-1 2,4'-(ethane-1,2-diyl)bis(methoxybenzene) 
• 100-09-4 4-methoxybenzoic acid 
• 26870-36-0 2-(4-hydroxyphenyl)benzo[b]furan 
• 14555-22-7 2-(2-methoxyphenyl)-2-(4-methoxyphenyl)acetonitrile 

Relevant articles and documents

(N-Heterocyclic Carbene)-Pd-catalyzed anaerobic oxidation of secondary alcohols and domino oxidation-arylation reactions

The use of commercially available (SIPr)Pd(cinnamyl)Cl (SIPr = 1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene) as a precatalyst for the anaerobic oxidation of secondary alcohols is described. The use of this complex allows for a drastic reduction in the reaction times and catalyst loading when compared to the unsaturated counterpart. This catalytic system is compatible with the use of microwave dielectric heating, decreasing even further catalyst loading and reaction times. Domino Pd-catalyzed oxidation-arylation reactions of secondary alcohols are also presented.(Figure Presented)

N-heterocyclic carbene-palladium-imine complex catalyzed α-arylation of ketones with aryl and heteroaryl chlorides under air atmosphere

A new structure of saturated ring skeleton monoligated NHC-Pd-Imine complex was easily synthesized and unambiguously confirmed by X-ray single crystal diffraction. It was found to be an efficient and air-stable catalyst for the α-arylation of ketones. The reaction could be operated in air without any negative effect. Non-activated aryl and heteroaryl chlorides have been successfully applied in the reaction with only 0.5 mol% catalyst loadings under air atmosphere. Excellent to good product yields were afforded.