65222-69-7

Basic information

• Product Name: Methyl-2-O-benzoyl-3,4,6-tridesoxy-α-D-erythro-hex-3-enopyranosid
• CAS NO: 65222-69-7
• Molecular Weight: 248.279
• Mol File: 65222-69-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Methyl-2-O-benzoyl-3,4,6-tridesoxy-α-D-erythro-hex-3-enopyranosid(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl-2-O-benzoyl-3,4,6-tridesoxy-α-D-erythro-hex-3-enopyranosid(65222-69-7)
• EPA Substance Registry System: Methyl-2-O-benzoyl-3,4,6-tridesoxy-α-D-erythro-hex-3-enopyranosid(65222-69-7)

Safety Data

• Hazardous Substances Data: 65222-69-7(Hazardous Substances Data)

Upstream product

• 100164-72-5 Methyl-3,4,6-tridesoxy-α-D-erythro-hex-3-enopyranosid 
• 65-85-0 benzoic acid 
• 98-88-4 benzoyl chloride 
• 5155-43-1 methyl 6-deoxy-α-D-glucopyranoside 
• 78391-93-2 Methyl-2-O-benzoyl-6-desoxy-α-D-glucopyranosid 

Downstream Products

• 61243-00-3 methyl 4-O-benzoyl-2,3,6-trideoxy-α-D-erythro-hex-2-enopyranoside 
• 61819-51-0 methyl-4-O-benzoyl-2,3,6-tridesoxy-α-D-threo-hex-2-enopyranoside 
• 78294-37-8 Methyl-2-O-acetyl-3,6-didesoxy-3-(4-methylphenylsulfonylamino)-α-D-altropyranosid 
• 78294-36-7 Methyl-2-O-acetyl-4,6-didesoxy-4-(4-methylphenylsulfonylamino)-α-D-altropyranosid 

Relevant articles and documents

Syntheses of Biologically Important Carbohydrates, 33. - Syntheses of Unsaturated Amino Sugars and Aminoalkyl-branched Carbohydrates via Sigmatropic Rearrangement of Trichloroacetimidates

Starting with the α-D-erythro-hex-3-enopyranoside 1 the isomers with β-D-erythro as well as α- and β-D-threo configuration 5b, 3b, and 9 are prepared.In Mitsunobu reactions the 1,2-cis derivatives 1 and 9 smoothly undergo SN2-type substitutions