65232-41-9Relevant articles and documents
Study of the reactivity of organonickel sigma-complexes towards nitriles
Gafurov,Sakhapov,Babaev,Dobrynin,Kurmaz,Metlushka,Rizvanov, I. Kh.,Shaikhutdinova,Sinyashin,Yakhvarov
, p. 254 - 259 (2017/07/11)
The reactivity of organonickel sigma-complexes of type [NiBr(Ar)(bpy)], where Ar = 2,6-dimethylphenyl (Xyl), 2,4,6-trimethylphenyl (Mes), 2,4,6-triisopropylphenyl (Tipp), 2,4,6-tricyclohexylphenyl (Tchp), bpy = 2,2′-bipyridine, towards nitriles (acetonitr
Synthesis of Aryl Ketones by the Pd-Catalyzed C-H Activation of Arenes and Intermolecular Carbopalladation of Nitriles
Zhou, Chengxiang,Larock, Richard C.
, p. 2302 - 2303 (2007/10/03)
The palladium-catalyzed reaction of simple arenes and nitriles provides good to excellent yields of aryl ketones or the corresponding hindered imines. The addition of a small amount of DMSO increases the yields dramatically. Both intermolecular and intramolecular examples of this process are successful. This novel chemistry is believed to involve palladium-catalyzed C?H activation, followed by carbopalladation of the nitrile. Copyright
Flash Vacuum Pyrolysis of 2-Methylbenzophenones and 2-Methyldiphenyl Ketimines
Gu, Taiyin Yang,Weber, William P.
, p. 2541 - 2544 (2007/10/02)
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