65325-65-7

Basic information

• Product Name: 1-chloro-4-[(fluoromethyl)sulfanyl]benzene
• Synonyms: 1-chloro-4-[(fluoromethyl)sulfanyl]benzene
• CAS NO: 65325-65-7
• Molecular Weight: 176.642
• Mol File: 65325-65-7.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 1-chloro-4-[(fluoromethyl)sulfanyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-chloro-4-[(fluoromethyl)sulfanyl]benzene(65325-65-7)
• EPA Substance Registry System: 1-chloro-4-[(fluoromethyl)sulfanyl]benzene(65325-65-7)

Safety Data

• Hazardous Substances Data: 65325-65-7(Hazardous Substances Data)

Upstream product

• 123-09-1 4-chlorophenyl methyl sulfide 
• 373-53-5 fluoroiodomethane 
• 106-54-7 p-Chlorothiophenol 
• 7205-90-5 chloromethyl 4-chlorophenyl sulfide 
• 107264-00-6 1-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate 
• 107263-95-6 N-fluoropyridinium triflate 

Downstream Products

• 65325-69-1 1-chloro-4-((fluoromethyl)sulfinyl)benzene 

Relevant articles and documents

Optimized Monofluoromethylsulfonium Reagents for Fluoromethylene-Transfer Chemistry

An investigation of the properties and reactivity of fluoromethylsulfonium salts resulted in the redesign of the reagents for fluoromethylene transfer chemistry. The model reaction, fluorocyclopropanation of nitrostyrene, turned out to be a suitable platf

Fluorination of sulfides using IF5-Et3N-3HF

Mono- and difluorinations of sulfides were achieved using a novel fluorinating reagent, IF5-Et3N-3HF. The reagent is applicable for substrates having various electron-withdrawing groups, such as an ester, amide, ketone, ni

Facile synthesis of α-fluoroalkyl sulfides under the oxidative desulfurization-fluorination conditions

Upon treatment with n-Bu4NH2F3 and 1,3-dibromo-5,5- dimethylhydantoin, various organic sulfides underwent a Pummerer-type rearrangement, followed by fluorination, to give α-fluoro sulfides. The fluoro-Pummerer rearrangement, when applied to RCH(SMe)CF2SMe, gave trifluoro sulfides RCF(SMe)CF2SMe. When an HF-pyridine reagent was used as the fluorinating agent, an oxidative desulfurization-fluorination reaction occurred depending on the structure of the substrates.