65350-60-9

Basic information

• Product Name: (E)-2-(vinylbenzenesulfonyl)vinylbenzene
• Synonyms: (E)-2-(vinylbenzenesulfonyl)vinylbenzene
• CAS NO: 65350-60-9
• Molecular Weight: 270.352
• Mol File: 65350-60-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (E)-2-(vinylbenzenesulfonyl)vinylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(vinylbenzenesulfonyl)vinylbenzene(65350-60-9)
• EPA Substance Registry System: (E)-2-(vinylbenzenesulfonyl)vinylbenzene(65350-60-9)

Safety Data

• Hazardous Substances Data: 65350-60-9(Hazardous Substances Data)

Upstream product

• 137325-91-8 (Z)-styrylsulfonyl acetic acid 
• 100-52-7 benzaldehyde 
• 100-42-5 styrene 
• 52147-97-4 trans 2-phenylethenesulfonyl chloride 
• 122-78-1 phenylacetaldehyde 
• 1015692-34-8 diisopropyl (diisopropoxyphosphorylmethylsulfonylmethyl)phosphonate 
• 622-24-2 2-phenylethyl chloride 
• 137524-38-0 2-(phenylethylsulfonyl)acetic acid 
• 99186-25-1 NSC₁₅₈₃₆₂ 
• 68667-91-4 (E)-2-chloro-2-phenylethyl styryl sulfone 
• 80223-52-5 bis-diethylphosphorylmethyl sulphone 
• 68667-98-1 (E)-1-(β-Phenylethylsulfonyl)-2-phenyl-ethen 
• 123-45-5 sulfonyldiacetic acid 

Downstream Products

• 59466-59-0 4ξ-methyl-3r,5c-diphenyl-[1,4]thiaphosphinane 1,1-dioxide 
• 59466-58-9 3r,4ξ,5c-triphenyl-[1,4]thiaphosphinane 1,1-dioxide 
• 135228-18-1 3,5-Diphenyl-4-methyltetrahydro-1,4-thiazine 1,1-Dioxide 
• 886-65-7 trans,trans-1,4-Diphenyl-1,3-butadiene 
• 135228-19-2 2,6-Diphenyl-1,4-dithiane 4,4-Dioxide 
• 1246658-37-6 C₁₈H₁₅NO₂S 
• 59466-66-9 4,4-dimethyl-1,1-dioxo-3r,5c-diphenyl-1-λ⁶-[1,4]thiaphosphinanium; iodide 
• 59466-64-7 4-methyl-3r,5c-diphenyl-[1,4]thiaphosphinane 1,1,4ξ-trioxide 
• 97132-66-6 (E)-5--1,5-diphenyl-3-thia-1-penten-3,3-dioxid 

Relevant articles and documents

Gram-scale synthesis of β-sulfonyl styrenes

A simple and gram-scale synthesis of β-sulfonyl styrenes has been developed starting from one-pot PPA (polyphosphoric acid)-catalyzed 1,1-diacetoxylation of arylacetaldehydes (ArCH2CHO) with acetic anhydride (Ac2O) followed by deacetoxylative sulfonylation of the resulting 1,1-diacetate intermediate with sodium sulfinates (RSO2Na) in good yields under solvent-free conditions.

SYNTHESIS OF (E,E)-BIS(ARYCYCLOPROPYL)SULFONES FROM NOVEL (E,E)-BIS(STYRYL)SULFONES

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Reaction of Alkenesulfonyl Chlorides with Olefins Catalyzed by a Ruthenium(II) Complex. A Novel Method for Synthesis of (E,E)-1,4-Diaryl-1,3-butadienes

In the presence of a catalytic amount of dichlorotris(triphenylphosphine)ruthenium(II) (1), alkenesulfonyl chloride (2) was found to react with vinylarenes to give 1:1 adducts (3) in high yield under mild conditions.Dehydrochlorination from the adducts 3 to afford divinyl sulfones (4) takes place by raising the reaction temperature from 80 to 130 deg C.Upon further reaction at 150 deg C, (E,E)-1,4-diaryl-1,3-butadienes (5) are formed in high yield if both of the alkenyl substituents of the sulfonyl chloride and the alkene have aryl groups.The time course of the reaction indicates that the addition of 2 to vinylarenes giving 1:1 adducts 3, dehydrochlorination from the adducts 3 giving divinyl sulfones 4, and desulfonylation from the divinyl sulfone 4 giving 1,3-butadienes 5 proceed successively.The usefulness of the reaction for the syntheses of (E,E)-1,4-diaryl-1,3-butadiene is described.On the other hand, 2 reacts with alkyl olefins in the presence of 1 to give 1:1 adducts (12) with extrusion of sulfur dioxide.