6538-93-8Relevant articles and documents
Synthesis of a new extended π-donor with 1,4-oxathiane annulation
Hellberg, Jonas,Balodis, Karlis,Moge, Mikael,Korall, Peter,Von Schuetz
, p. 31 - 34 (1997)
4,5;4′,5′-Bis(1,4-oxathiane-2,3-diyldithio)tetrathiafulvalen e 7 (TOET) is synthesised in four steps from 1,4-oxathiane. Compound 7 shows two reversible redox couples at 0.56 and 0.90 V vs. SCE. Analysis of NMR spectra combined with energy minimisation calculations indicated that at least three isomers of TOET should be present in solution. TOET forms a charge-transfer complex with TCNQ which shows a conductivity of 3 x 10-3 S cm-1.
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Parham et al.
, p. 1824 (1952)
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