65392-64-5

Basic information

• Product Name: N,N-dipropan-2-yl-1,4-ditert-butyl-tetrazaphosphol-5-amine
• Synonyms: N,N-dipropan-2-yl-1,4-ditert-butyl-tetrazaphosphol-5-amine
• CAS NO: 65392-64-5
• Molecular Formula: C14H32N5P
• Molecular Weight: 301.41
• Mol File: 65392-64-5.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 318.3°C at 760 mmHg
• Flash Point: 146.3°C
• Appearance: /
• Vapor Pressure: 0.000363mmHg at 25°C
• CAS DataBase Reference: N,N-dipropan-2-yl-1,4-ditert-butyl-tetrazaphosphol-5-amine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dipropan-2-yl-1,4-ditert-butyl-tetrazaphosphol-5-amine(65392-64-5)
• EPA Substance Registry System: N,N-dipropan-2-yl-1,4-ditert-butyl-tetrazaphosphol-5-amine(65392-64-5)

Safety Data

• Hazardous Substances Data: 65392-64-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H32N5P/c1-11(2)17(12(3)4)20-18(13(5,6)7)15-16-19(20)14(8,9)10/h11-12H,1-10H3

Upstream product

• 13686-33-4 t-butyl azide 
• 63950-84-5 (tert-Butylimino)(diisopropylamino)phosphan 

Relevant articles and documents

Synthesis and Decomposition of λ3- and λ5-Tetrazaphospholenes

Iminophosphanes 4a - c react with tert-butyl azide by -cycloaddition to give λ3-tetrazaphospholenes 8a - c.These compounds decompose thermally or photochemically by N2-elimination, forming diiminophosphoranes 9a, b, b', c by intramolecular oxidation of the phosphorus atom, where 9c can only be captured as its -cycloaddition products 11c and 12c.The reaction of the diiminophosphoranes 7a, 9a, and 9c with tert-butyl or ethyl azide yields the λ5-tetrazaphospholenes 10a', 10c - g.Compounds of this type (10i', h) are also a available by the reaction of 4b, c with ethyl azide.In contrast to the λ3-tetrazaphospholene system 8, the oxidized form 10 -cycloreverses thermally as shown for 10a', while photochemically forms the λ5-diazaphosphoridine 14 under N2-elimination.The NMR data and the decomposition of the tetrazaphospholenes are discussed.