65418-75-9

Basic information

• Product Name: 3-(4-METHOXY-PHENYL)-1-(4-METHYLPHENYL)-PROPYNONE
• Synonyms: 3-(4-METHOXY-PHENYL)-1-(4-METHYLPHENYL)-PROPYNONE
• CAS NO: 65418-75-9
• Molecular Formula: C₁₇H₁₄O₂
• Molecular Weight: 250.29186
• Mol File: 65418-75-9.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 402.4°C at 760 mmHg
• Flash Point: 178.3°C
• Appearance: /
• Density: 1.14g/cm³
• Vapor Pressure: 1.1E-06mmHg at 25°C
• Refractive Index: 1.599
• CAS DataBase Reference: 3-(4-METHOXY-PHENYL)-1-(4-METHYLPHENYL)-PROPYNONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-METHOXY-PHENYL)-1-(4-METHYLPHENYL)-PROPYNONE(65418-75-9)
• EPA Substance Registry System: 3-(4-METHOXY-PHENYL)-1-(4-METHYLPHENYL)-PROPYNONE(65418-75-9)

Safety Data

• Hazardous Substances Data: 65418-75-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C17H14O2/c1-13-3-8-15(9-4-13)17(18)12-7-14-5-10-16(19-2)11-6-14/h3-6,8-11H,1-2H3

Upstream product

• 201230-82-2 carbon monoxide 
• 5395-43-7 tri(p-tolyl)antimony 
• 624-31-7 4-tolyl iodide 
• 768-60-5 4-methoxyphenylacetylen 
• 874-60-2 4-methyl-benzoyl chloride 
• 696-62-8 para-iodoanisole 
• 3989-14-8 (4-methoxyphenylethynyl)trimethylsilane 
• 104-87-0 4-methyl-benzaldehyde 
• 99-94-5 p-Toluic acid 

Downstream Products

• 1358811-60-5 ethyl 5-(4-methoxyphenyl)-3-(p-tolyl)thiophene-2-carboxylate 
• 65205-51-8 3-(4′-methoxyphenyl)-5-(4″-methylphenyl)isoxazole 

Relevant articles and documents

Synthesis and Characterization of Ag@g?C3N4 and Its Photocatalytic Evolution in Visible Light Driven Synthesis Of Ynone

The primary aim of this work is to synthesize photocatalyst to promote the synthesis of ynones. In this context, we synthesized AgNPs@g?C3N4 nanocomposite. The nanocomposite was characterized by using SEM, HR-TEM, XRD, EDS, ICP-AES,

Synthesis of Water-Soluble Blue-Emissive Tricyclic 2-Aminopyridinium Salts by Three-Component Coupling-(3+3)-Anellation

The (3+3) anellation of alkynones and cyclic amidines is a novel and unexpected approach to generate intensively blue luminescent tricyclic 2-aminopyridinium salts with quantum yields Φf up to 63 % in water. By implementation into a consecutive three-component reaction, these title compounds are obtained rapidly and efficiently in a diversity-oriented fashion. Most interestingly, these bi- and tricyclic 2-aminopyridinium salts emit in dichloromethane and water solutions, thus making them interesting novel luminophore probes for bioanalytics, as well as in the solid state, thus making them blue emitters with tunable efficiency.

A highly efficient heterogeneous palladium-catalyzed cascade three-component reaction of acid chlorides, terminal alkynes and hydrazines leading to pyrazoles

In the presence of 0.5 mol% of 3-(2-aminoethylamino)propyl-functionalized MCM-41-immobilized palladium(II) complex [MCM-41-2N-Pd(OAc)2] and 1.0 mol% of CuI, acid chlorides were coupled with terminal alkynes in Et3N at 50 °C to give α,β-unsaturated ynones, which were converted in situ into pyrazoles by the cycloaddition of hydrazines at room temperature with acetonitrile as cosolvent. The cascade reactions generated a variety of pyrazole derivatives in moderate to good yields, and this heterogeneous palladium catalyst exhibited higher catalytic activity than PdCl2(PPh3)2 and could be recovered and reused for at least 10 consecutive trials without any decreases in activity.