65801-55-0Relevant articles and documents
Synthesis of α-arylated allylsilanes through palladium-catalyzed γ-selective allyl-aryl coupling
Li, Dong,Tanaka, Tatsunori,Ohmiya, Hirohisa,Sawamura, Masaya
supporting information; experimental part, p. 3344 - 3347 (2010/11/03)
(Equation Presented). A palladium-catalyzed γ-selective allyl-aryl coupling between γ-silylated allylic esters and arylboronic acids produced α-arylated allylsilanes with E-alkene geometry. The reaction tolerated various functional groups in both the arylboronic acids and the allylic esters and afforded functionalized allylsilanes. The reaction of optically active allylic esters took place with excellent α-to-γ chirality transfer with syn stereochemistry to give chiral allylsilanes.