65814-11-1

Basic information

• Product Name: Benzaldehyde, 4-methoxy-, (2,6-dimethylphenyl)hydrazone
• CAS NO: 65814-11-1
• Molecular Formula: C16H18N2O
• Molecular Weight: 254.332
• Mol File: 65814-11-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 4-methoxy-, (2,6-dimethylphenyl)hydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 4-methoxy-, (2,6-dimethylphenyl)hydrazone(65814-11-1)
• EPA Substance Registry System: Benzaldehyde, 4-methoxy-, (2,6-dimethylphenyl)hydrazone(65814-11-1)

Safety Data

• Hazardous Substances Data: 65814-11-1(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 603-77-0 (2,6-dimethylphenyl)hydrazine 

Downstream Products

• 65814-14-4 3-(4-amino-3,5-dimethylphenyl)-4-methoxybenzaldehyde 

Relevant articles and documents

Rearrangement of arylhydrazones of aromatic and arylaliphatic carbonyl compounds to biphenyl derivatives. 3

The behavior toward polyphosphoric acid of arylhydrazones of aromatic carbonyl compounds (anisaldehyde, substituted benzophenones, (4-methoxyphenyl)glyoxylic acid esters) and arylaliphatic ketones (4-methoxy- and 4-aminoacetophenone) is described.Biphenyl derivatives are formed through a sigmatropic rearrangement, which often occurs in competition with the expected Fischer indole synthesis and, in the case of the 4-amino-acetophenone 2,6-dimethylphenylhydrazone, with a completely new sigmatropic rearrangement.