65877-63-6

Basic information

• Product Name: 3-O-Benzyl-alpha-D-mannopyranose
• Synonyms: 3-O-Benzyl-alpha-D-mannopyranose;3-O-Benzyl-D-mannopyranoside;3-O-(PhenylMethyl)-α-D-Mannopyranose
• CAS NO: 65877-63-6
• Molecular Formula: C₁₃H₁₈O₆
• Molecular Weight: 270.27842
• Product Categories: 13C & 2H Sugars;Carbohydrates & Derivatives
• Mol File: 65877-63-6.mol
• Article Data: 25

Chemical Properties

• Boiling Point: 493.386°C at 760 mmHg
• Flash Point: 252.191°C
• Appearance: /
• Density: 1.409g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.612
• Solubility: Dichloromethane, Ethyl Acetate
• PKA: 12.05±0.70(Predicted)
• CAS DataBase Reference: 3-O-Benzyl-alpha-D-mannopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-O-Benzyl-alpha-D-mannopyranose(65877-63-6)
• EPA Substance Registry System: 3-O-Benzyl-alpha-D-mannopyranose(65877-63-6)

Safety Data

• Hazardous Substances Data: 65877-63-6(Hazardous Substances Data)

Usage

Chemical Properties

Amorphous White Powder

InChI:InChI=1/C13H18O6/c14-6-9-10(15)12(11(16)13(17)19-9)18-7-8-4-2-1-3-5-8/h1-5,9-17H,6-7H2/t9?,10-,11?,12+,13+/m1/s1

Upstream product

• 52560-18-6 3-O-Benzyl-1,2;5,6-di-O-cyclohexyliden-α-D-allofuranose 
• 22331-21-1 1,2:5,6-di-O-isopropylidene-3-O-benzyl-α-D-allofuranose 
• 18685-18-2 3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose 
• 591727-19-4 1-2,5-6 di-O-isopropylidene 3-O-benzyl α(D)gluco-pentoaldofuranose 
• 100-44-7 benzyl chloride 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 42926-89-6 1,2-O-isopropylidene-3-O-benzyl-α-D-glucofuranose 
• 65827-58-9 1,2,4,6-tetra-O-acetyl-3-O-benzyl-α-D-mannopyranoside 
• 530-26-7 D-Mannose 
• 100-39-0 benzyl bromide 
• 101475-83-6 3-O-benzyl-1,2;5,6-di-O-isopropylidene-α-D-glucofuranoside 
• 18685-18-2 3-O-benzyl-1,2:5,6-di-O-isopropylidene-D-glucofuranose 
• 118711-49-2 1,2,4,6-tetra-O-acetyl-3-O-benzyl-L-idopyranoside 
• 22331-19-7 3-O-benzyl-1,2-O-isopropylidene-5,6-di-O-mesyl-α-D-glucofuranose 

Downstream Products

• 70797-87-4 2-O-Benzyl-4-O-formyl-D-ribose 
• 87791-16-0 3-O-Benzyl-1,2,4,6-tetra-O-pivaloyl-β-D-glucopyranose 
• 39686-94-7 1,2,4,6-tetra-O-acetyl-3-O-benzyl-β-D-glucopyranose 
• 103082-79-7 1,2,4,6-tetra-O-acetyl-3-O-benzyl-α-D-glucopyranose 
• 149067-49-2 1,2,4,6-tetra-O-benzoyl-3-O-benzyl-β-D-allopyranose 
• 27531-35-7 4-O-benzyl-D-glycero-D-gulo-heptono-1,5-lactone 
• 158775-55-4 4-O-benzyl-D-glycero-D-allo-heptono-1,5-lactone 
• 181228-44-4 1,2,4,6-tetra-O-benzoyl-3-O-benzyl-L-idopyranose 
• 187961-71-3 methyl 3-O-benzyl-β-D-mannopyranosyl-(1-4)-2,3,6-tri-O-benzoyl-α-D-glucopyranoside 
• 30572-04-4 1,2,4,6-tetra-O-benzoyl-3-O-benzyl-β-D-glucopyranoside 
• 485812-46-2 3-O-benzyl-D-glucono-1,4-lactone 

Relevant articles and documents

ACIDIC DYSTROGLYCAN OLIGOSACCHARIDE COMPOUND AND METHOD FOR MAKING SAME

A synthetic dystroglycan oligosaccharide comprising Formula (I) wherein a repeating disaccharide motif consists of Glucuronic Acid (ClcA) and Xylose (Xyl) having a defined glycosyl connection GlcA-β-(1→3)-Xyl-α-(1→3)-GlcA; wherein either end of the synthetic dystroglycan oligosaccharide is conjugatable with chemical or biological vehicle or support; wherein the non-reducing terminal (II) is conjugatable with any oligosaccharides or groups that can modify a hydroxyl functionality; and wherein the reducing terminal is conjugatable with any tags, oligosaccharides or anything that can modify a hydroxyl functionality.

Preparation method of clostridium bolteae surface capsular polysaccharide structure derivative

The invention discloses a preparation method of a clostridium bolteae surface capsular polysaccharide structure derivative and belongs to the field of sugar chemistry. The preparation method comprisesthe following steps: taking glucose as a glycosyl donor to obtain a target beta-glycosidic bond; then successfully synthesizing a disaccharide building block through an oxidization-reduction glucoseC-2 site method; then synthesizing a target oligosaccharide structure which takes the disaccharide building block as a repeating unit, such as the gram-positive bacterium surface capsular polysaccharide structure derivative [arrow3]-alpha-D-Manp-(1arrow4)-beta-D-Rhap-(1arrow]5-Linker. A reducing end of decaose is connected with a connecting arm and is used for connecting protein to form a glycoconjugate for carrying out immunology researches. The method provided by the invention has the advantages of simplicity, time saving, labor saving and low cost; the obtained clostridium bolteae surface capsular polysaccharide structure derivative is possibly used for developing and preparing medicine related to autism.

A carbohydrate-based approach for the total synthesis of (-)-dinemasone B, (+)-4a-epi-dinemasone B, (-)-7-epi-dinemasone B, and (+)-4a,7-di-epi-dinemasone B

(-)-Dinemasone B was isolated by Krohn and co-workers from a culture of the endophytic fungus Dinemasporium strigosum and has shown promising antimicrobial activity. Described herein is the first total synthesis of (-)-dinemasone B, (+)-4a-epi-dinemasone B, (-)-7-epi-dinemasone B, and (+)-4a,7-di-epi-dinemasone B. Their absolute configurations were also determined. The developed synthesis features a stereoselective reduction of C-glycosidic ketone, lactonization, and E-olefination of aldehyde starting from d-glucose.