66270-75-5

Basic information

• Product Name: Silane, (2-cyclohexylethenyl)trimethyl-, (Z)-
• CAS NO: 66270-75-5
• Molecular Formula: C11H22Si
• Molecular Weight: 182.381
• Mol File: 66270-75-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Silane, (2-cyclohexylethenyl)trimethyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (2-cyclohexylethenyl)trimethyl-, (Z)-(66270-75-5)
• EPA Substance Registry System: Silane, (2-cyclohexylethenyl)trimethyl-, (Z)-(66270-75-5)

Safety Data

• Hazardous Substances Data: 66270-75-5(Hazardous Substances Data)

Upstream product

• 66270-60-8 (cyclohexylethynyl)trimethylsilane 
• 67-56-1 methanol 
• 76346-96-8 C₁₁H₂₁LiSi 
• 110-82-7 cyclohexane 
• 1066-54-2 trimethylsilylacetylene 
• 1568-65-6 bis(cyclohexanyl)borane 
• 336193-41-0 2-chloro-1-cyclohexyl-2-(trimethylsilyl)ethyl acetate 
• 29955-07-5 trimethyl(diiodomethyl)silane 
• 2043-61-0 cyclohexanecarbaldehyde 
• 336193-49-8 2-chloro-1-cyclohexyl-2-trimethylsilanyl-ethanol 
• 931-48-6 2-cyclohexylacetylene 

Downstream Products

• 67404-71-1 (E)-(2-chloroethenyl)cyclohexane 
• 67478-59-5 (E)-1-bromo-2-cyclohexyl-1-ethene 
• 67404-69-7 (Z)-1-iodo-2-cyclohexyl-1-ethene 
• 1192889-76-1 2-cyclohexyl-3-phenyl-3-(trimethylsiloxy)propene 

Relevant articles and documents

Platinum-catalyzed nucleophilic addition of vinylsilanes at the β-position

In the presence of catalytic amounts of PtCl2 and metal Iodides, β-substituted vlnylsllanes reacted with aldehydes at the β-position to give allyl silyl ethers. The Pt-catalyzed addition to aromatic aldehydes proceeded efficiently in the presence of Lil. The combined use of PtCl 2 and Mnl2 was found to be effective In addition to aliphatic aldehydes.

Synthesis of (Z)-vinylsilanes with high diastereoselectivity by using samarium diiodide

matrix presented β-Elimination of O-acetyl 1-chloro-1-trimethylsilylalkan-2-ols 1 was achieved by using samarium diiodide as a metaling reagent and afforded the corresponding (Z)-vinylsilanes with high stereoselectivity. The starting compounds 1 were easi

The Hydroboration of (Trimethylsilyl)ethyne with Dialkylboranes and its Application to the Synthesis of (E)-1-(Trimethylsilyl)alk-1-enes and 2-(Trimethylsilyl)alk-1-enes

The reaction of (trimethylsilyl)ethyne 1 with a stoicheiometric amount of dialkylborane 2 proceeds to the monohydroboration stage, giving a mixture of regioisomers, (E)-dialkylborane 3 and dialkylborane 4.In the hydroboration with bulky dialkylboranes, derived from internal alkenes, the former predominates.Successive treatment of the mixture with methyllithium and benzenesulphenyl chloride exclusively affords highly pure (E)-2-alkyl-1-(trimethylsily)ethene 6 whose alkyl group migrates from the boron atom, while in the hydroboration with less bulky dialkylboranes, derived from terminal alkenes, the latter predominates.Successive treatment of the mixture with aq.NaOH and iodine exclusively affords highly pure 2-(trimethylsilyl)alk-1-ene 7 whose alkyl group migrates from the boron atom.