663611-28-7

Basic information

• Product Name: Fe[(C₅H₄)N(COCH₃)C₆H₃(CH₃)2]2
• CAS NO: 663611-28-7
• Molecular Weight: 508.443
• Mol File: 663611-28-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Fe[(C₅H₄)N(COCH₃)C₆H₃(CH₃)2]2(CAS DataBase Reference)
• NIST Chemistry Reference: Fe[(C₅H₄)N(COCH₃)C₆H₃(CH₃)2]2(663611-28-7)
• EPA Substance Registry System: Fe[(C₅H₄)N(COCH₃)C₆H₃(CH₃)2]2(663611-28-7)

Safety Data

• Hazardous Substances Data: 663611-28-7(Hazardous Substances Data)

Upstream product

• 1293-65-8 1,1'-dibromoferrocene 

Relevant articles and documents

1,1′-Di(arylamino)ferrocenes. A new family of privileged [N,N] ligands with tunable steric control for applications in homogeneous organometallic catalysis and coordination chemistry

Fe[(C5H4)NHPh]2 (2a) was prepared from 1,1′-dibromoferrocene and N-phenylacetamide by an Ullmann reaction and subsequent basic solvolysis of the coupling product Fe[(C5H 4)N(COMe)Ph]2 (1a). This solvolysis failed in the case of the bulkier Fe[(C5H4)N(COMe)(2,6-Me2C 6H3)]2 (1b). Fe[(C5H 4)N(2,6-Me2C6H3)]2 (2b) and Fe[(C5H4)N(2,4,6-iPr3C6H 2)]2 (2c) were obtained by Hartwig-Buchwald type cross-coupling of 1,1′-diaminoferrocene with the respective aryl bromide.