66397-25-9

Basic information

• Product Name: p-Nitrophenyl allenyl ether
• Synonyms: p-Nitrophenyl allenyl ether
• CAS NO: 66397-25-9
• Molecular Weight: 177.159
• Mol File: 66397-25-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: p-Nitrophenyl allenyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: p-Nitrophenyl allenyl ether(66397-25-9)
• EPA Substance Registry System: p-Nitrophenyl allenyl ether(66397-25-9)

Safety Data

• Hazardous Substances Data: 66397-25-9(Hazardous Substances Data)

Upstream product

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Relevant articles and documents

Novel One-Pot Synthetic Method for Propargyl Alcohol Derivatives from Allyl Alcohol Derivatives

An efficient one-pot procedure for the synthesis of propargyl alcohol derivatives from allyl alcohol derivatives has been developed. The key to this transformation from a C-C double bond to a C-C triple bond is that hydrogen bromide elimination from 1,2-dibromoalkanes that contain a neighboring oxygen functional group is promoted by the inductive electron-withdrawing effect of the oxygen functional group. In the one-pot reaction, tetrabutylammonium hydroxide was the best base, and the addition of molecular sieves 13X also promoted the reaction.

Site-selective and regioselective Diels-Alder reaction of allenyl aryl ethers

The site-selectivity and regioselectivity of Diels-Alder reactions of allenyl aryl ethers with cyclopentadiene and acrolein were studied. While cyclopentadiene (as an electron-rich diene) only reacted with the external double bond of allenyl aryl ethers t

Microwave promoted rapid isomerisation of propargyl ethers into allenyl ethers

Aryl or alkyl propargyl ethers have been isomerized efficiently with good to excellent yield into corresponding allenyl ethers in the presence of potassium tert-butoxide under the microwave irradiation.