665033-45-4

Basic information

• Product Name: Silane, (1,1-dimethylethyl)dimethyl[[3-(2-nitrophenyl)-2-propynyl]oxy]-
• CAS NO: 665033-45-4
• Molecular Formula: C15H21NO3Si
• Molecular Weight: 291.422
• Mol File: 665033-45-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silane, (1,1-dimethylethyl)dimethyl[[3-(2-nitrophenyl)-2-propynyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1,1-dimethylethyl)dimethyl[[3-(2-nitrophenyl)-2-propynyl]oxy]-(665033-45-4)
• EPA Substance Registry System: Silane, (1,1-dimethylethyl)dimethyl[[3-(2-nitrophenyl)-2-propynyl]oxy]-(665033-45-4)

Safety Data

• Hazardous Substances Data: 665033-45-4(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 80151-24-2 3-(2-nitro-phenyl)-prop-2-yn-1-ol 
• 577-19-5 2-nitrophenyl bromide 
• 609-73-4 o-nitroiodobenzene 

Downstream Products

• 665033-47-6 2-(3-tert-butyldimethylsilyloxy-1-propynyl)aniline 
• 664981-88-8 N-{2-[3-(tert-butyl-dimethyl-silanyloxy)-prop-1-ynyl]-phenyl}-4-methyl-benzenesulfonamide 
• 665033-49-8 N-[2-(3-hydroxy-prop-1-ynyl)-phenyl]-4-methyl-benzenesulfonamide 

Relevant articles and documents

Et2Zn-catalyzed intramolecular hydroamination of alkynyl sulfonamides and the related tandem cyclization/addition reaction

(Chemical Equation Presented) Intramolecular hydroamination of alkynyl amides was effected by a catalytic amount of Et2Zn (20 mol %) to form indole derivatives, and a tandem cyclization/nucleophilic addition procedure involving reaction of the indole zinc salt intermediate with acid chlorides or halides was developed to provide an efficient approach to C3-substituted indole derivatives when an excess of Et2Zn (120 mol %) was used.