66536-78-5

Basic information

• Product Name: (+)-(R)-1-(p-tolylsulfinyl)-2-propanone
• Synonyms: (+)-(R)-1-(p-tolylsulfinyl)-2-propanone
• CAS NO: 66536-78-5
• Molecular Weight: 196.27
• Mol File: 66536-78-5.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: (+)-(R)-1-(p-tolylsulfinyl)-2-propanone(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(R)-1-(p-tolylsulfinyl)-2-propanone(66536-78-5)
• EPA Substance Registry System: (+)-(R)-1-(p-tolylsulfinyl)-2-propanone(66536-78-5)

Safety Data

• Hazardous Substances Data: 66536-78-5(Hazardous Substances Data)

Upstream product

• 1200-13-1 1-(p-tolylsulfanyl)propan-2-one 
• 83859-12-5 N,N-Dimethyl-N'-[1-methyl-2-((R)-toluene-4-sulfinyl)-eth-(E)-ylidene]-hydrazine 
• 106353-39-3 Methyl 3-oxo-4-<(R)-p-tolylsulfinyl>butyrate 
• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 141-78-6 ethyl acetate 
• 5056-07-5 (S)-methyl p-tolyl sulfoxide 
• 75-05-8 acetonitrile 
• 1517-82-4 (1R,2S,5R,SS)-(-)-menthyl p-toluenesulfinate 
• 1517-82-4 (-)-menthyl p-toluenesulfinate 
• 56742-98-4 1-<(4-methylphenyl)sulphinyl>propan-2-one 

Downstream Products

• 113002-31-6 (3S)-(R_S)-3-benzyloxymethyl-3,4-dihydro-6-methyl-5-p-tolylsulfinyl-2H-pyran 
• 113002-27-0 [(R)-6-Methyl-5-((R)-toluene-4-sulfinyl)-3,4-dihydro-2H-pyran-3-yl]-methanol 
• 113002-27-0 [(S)-6-Methyl-5-((S)-toluene-4-sulfinyl)-3,4-dihydro-2H-pyran-3-yl]-methanol 
• 113002-35-0 [(R)-6-Methyl-5-((S)-toluene-4-sulfinyl)-3,4-dihydro-2H-pyran-3-yl]-methanol 
• 113002-30-5 (R)-1-Methyl-7-((S)-toluene-4-sulfinyl)-2,6-dioxa-bicyclo[2.2.2]octane 
• 113002-30-5 (S)-1-Methyl-7-((S)-toluene-4-sulfinyl)-2,6-dioxa-bicyclo[2.2.2]octane 
• 136680-13-2 (4aR,6aS,10aS,10bR)-4a,7,7,10a-Tetramethyl-3-((R)-toluene-4-sulfinylmethyl)-4a,5,6,6a,7,8,9,10,10a,10b-decahydro-1H-benzo[f]chromene 
• 136778-14-8 (4aS,6aR,10aR,10bS)-4a,7,7,10a-Tetramethyl-3-((R)-toluene-4-sulfinylmethyl)-4a,5,6,6a,7,8,9,10,10a,10b-decahydro-1H-benzo[f]chromene 
• 136680-12-1 (4aR,8aR)-5,5,8a-Trimethyl-2-((R)-toluene-4-sulfinylmethyl)-4a,5,6,7,8,8a-hexahydro-4H-chromene 
• 136680-16-5 (4aS,8aS)-5,5,8a-Trimethyl-2-((R)-toluene-4-sulfinylmethyl)-4a,5,6,7,8,8a-hexahydro-4H-chromene 
• 142075-98-7 (2R,3S,R_S)-3-(p-tolylsulfinyl)butan-2-ol 
• 142184-57-4 (2R,3R,R_S)-3-(p-tolylsulfinyl)butan-2-ol 
• 144830-29-5 (1R,(S)R)-N-benzyl-1-methyl-2-(p-tolylsulfinyl)ethylamine 
• 144830-30-8 Benzyl-[(S)-1-methyl-2-((R)-toluene-4-sulfinyl)-ethyl]-amine 

Relevant articles and documents

The synthesis of chiral β-ketosulfoxides by enantioselective oxidation and their stereocontrolled reduction to β-hydroxysulfoxides

Various chiral non-racemic β-ketosulfoxides, a class of compounds frequently used in asymmetric synthesis, were prepared in good yields by tert-butyl hydroperoxide oxidation of the corresponding sulfides in the presence of a complex between titanium and (

A new and general synthesis of chiral β-ketosulfoxides by reaction of (+)-(R)-methyl p-tolyl sulfoxide with nitriles

The nitrile functional group is efficiently transformed into the β-ketosulfoxide moiety by reaction with the anion formed from (+)-(R)-methyl p-tolyl sulfoxide and aqueous acidic work-up of the reaction.

Studies on chiral organosulfur compounds. III. Lewis acid-catalyzed intramolecular asymmetric pericyclic reactions of chiral α-acetyl and methoxycarbonylvinylic sulfoxides

A chiral α-sulfinyl α,β-unsaturated ketone served as a good chiral diene or enophile in intramolecular Lewis acid-catalyzed asymmetric pericyclic reactions, giving hetero-Diels-Alder reaction products, together with ene reaction products in some cases, in