66553-02-4Relevant articles and documents
Electrochemical reduction of lindane using a cobaloxime containing electron-withdrawing groups
Pizarro, Sebastián,Gallardo, Miguel,Gajardo, Francisco,Delgadillo, Alvaro
, p. 164 - 166 (2019)
The cobaloxime [CoCl(dbegH)2(py)] where dbegH is 4,4′?((1E,2E)?1,2?bis(hydroxyimino)ethane?1,2?diyl)dibenzoate and py is pyridine was synthesized. The electrochemical behavior was studied using cyclic voltammetry. A reversible Co(II)/Co(I) wave
A rare (3,12)-connected zirconium metal-organic framework with efficient iodine adsorption capacity and pH sensing
Guo, Bingbing,Li, Fugang,Wang, Chiming,Zhang, Liangliang,Sun, Daofeng
, p. 13173 - 13179 (2019/06/06)
We report here a stable rare zirconium metal-organic framework (MOF) exhibiting a sky topology, Zr6(μ3-O)4(μ3-OH)4(ITTC)4 (UPC-158) (where H3ITTC = 4,4′,4′′-(1H-imidazole-2,4,5-t
Introduction of carbonyl groups: An approach to enhance electrochemical performance of conjugated dicarboxylate for Li-ion batteries
Medabalmi, Veerababu,Ramanujam, Kothandaraman
, p. A1720 - A1725 (2017/06/21)
A rational functionalization of conjugated dicarboxylate is reported here to enhance the cyclability and rate capability for Li-ion batteries. Introduction of carbonyl groups between aromatic rings is explored as an alternative way to extend π-conjugation. For the proof of concept, 4,4′-bis(lithiooxycarbonyl)benzil (Li2-BZL) was synthesized and compared its lithium storage performance against lithium [1,1′-biphenyl]-4,4′-dicarboxylate (Li2-BPDC). The Li2-BZL electrode delivers a stable capacity of 165 mAh g?1 even after 50 cycles at current density of 50 mAh g?1 whereas, rapid capacity fading was observed in the case of Li2-BPDC. Density functional theory (DFT) studies confirmed that the carbonyl groups in the Li2-BZL to reduce the bandgap, thereby improving the elctrochemical lithium storage performance of Li2-BZL electrode in comparision to that of Li2-BPDC.