66777-99-9

Basic information

• Product Name: N-phenylpentadecanamide
• CAS NO: 66777-99-9
• Molecular Formula: C₂₁H₃₅NO
• Molecular Weight: 317.5087
• Mol File: 66777-99-9.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 468°C at 760 mmHg
• Flash Point: 290.2°C
• Density: 0.941g/cm³
• Vapor Pressure: 6.24E-09mmHg at 25°C
• Refractive Index: 1.509
• CAS DataBase Reference: N-phenylpentadecanamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-phenylpentadecanamide(66777-99-9)
• EPA Substance Registry System: N-phenylpentadecanamide(66777-99-9)

Safety Data

• Hazardous Substances Data: 66777-99-9(Hazardous Substances Data)

Upstream product

• 1002-84-2 palmitic acid 
• 62-53-3 aniline 
• 1120-36-1 1-tetradecene 
• 201230-82-2 carbon monoxide 
• 2210-24-4 N-acryloylaniline 
• 10157-76-3 dodecyl 4-methylbenzenesulphonate 

Relevant articles and documents

-

-

A preparation method of the fatty amide

The invention discloses a preparation method for fatty acyl amide, belonging to the technical field of organic chemical synthesis. The method comprises the following steps: using substituted terminal olefin, carbon monoxide, and aminal or amine as raw materials, then carrying out catalyzation or co-catalyzation with aldehyde via a transition metal catalyst, and carrying out reaction in an organic solvent at 50 to 120 DEG C for 12 to 24 hours under the participation of a ligand or the co-participation of the ligand with an additive; removing the organic solvent when the reaction is completed, and carrying out column chromatography so as to obtain a fatty acyl amide compound. The preparation method for the fatty acyl amide has the following advantages: the raw materials, the catalyst and the additive for the reaction are cheap and easily available; synthetic process is simple; synthetic cost is greatly reduced; reaction conditions are mild; industrialization is easily realized; the raw materials and the catalyst for the reaction are clean and non-toxic and has small pollution to the environment.

Palladium-catalyzed hydroaminocarbonylation of alkenes with amines: A strategy to overcome the basicity barrier imparted by aliphatic amines

A novel and efficient palladium-catalyzed hydroaminocarbonylation of alkenes with aminals has been developed under mild reaction conditions, and allows the synthesis of a wide range of N-alkyl linear amides in good yields with high regioselectivity. On the basis of this method, a cooperative catalytic system operating by the synergistic combination of palladium, paraformaldehyde, and acid was established for promoting the hydroaminocarbonylation of alkenes with both aromatic and aliphatic amines, which do not react well under conventional palladium-catalyzed hydroaminocarbonylation. Back to basics: The basicity of aliphatic amines precludes their use in the palladium-catalyzed hydroaminocarbonylation. This issue was overcome by using aminals as surrogates of aliphatic amines. A cooperative catalytic system was discovered to operate by the synergistic combination of palladium, paraformaldehyde, and acid for promotion of the hydroaminocarbonylation of alkenes with both aromatic and aliphatic amines.