66854-78-2

Basic information

• Product Name: (S)-N-(benzyloxycarbonyl)valylimidazolide
• Synonyms: (S)-N-(benzyloxycarbonyl)valylimidazolide
• CAS NO: 66854-78-2
• Molecular Weight: 301.345
• Mol File: 66854-78-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (S)-N-(benzyloxycarbonyl)valylimidazolide(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-N-(benzyloxycarbonyl)valylimidazolide(66854-78-2)
• EPA Substance Registry System: (S)-N-(benzyloxycarbonyl)valylimidazolide(66854-78-2)

Safety Data

• Hazardous Substances Data: 66854-78-2(Hazardous Substances Data)

Upstream product

• 501-53-1 benzyl chloroformate 
• 72-18-4 L-valine 
• 1149-26-4 (S)-N-(benzyloxycarbonyl)valine 
• 530-62-1 1,1'-carbonyldiimidazole 
• 288-32-4 1H-imidazole 

Downstream Products

• 124817-99-8 (3S,4R)-andrimid 
• 1345680-37-6 (S)-methyl 2-(3-((S)-1-(benzyloxycarbonylamino)-2-methylpropyl)ureido)-3-phenylpropanoate 
• 95187-97-6 4-(benzyloxycarbonyl)amino-5-methyl-3-oxohexansaeure-aethylester 
• 234752-13-7 (5S)-3-methyl-5-(2-propyl)pyrrolidine-2,4-dione 
• 234752-14-8 methyl (3S)-2,5-dimethyl-3-oxo-4-[(N-phenylmethoxycarbonyl)amino]hexanoate 
• 118916-87-3 (S)-ethyl 4-(benzyloxycarbonylamino)-5-methyl-3-oxohexanoate 
• 137271-80-8 [(S)-2-Methyl-1-((3R,4S)-4-methyl-2,5-dioxo-pyrrolidine-3-carbonyl)-propyl]-carbamic acid benzyl ester 
• 137331-58-9 [(S)-2-Methyl-1-((3S,4R)-4-methyl-2,5-dioxo-pyrrolidine-3-carbonyl)-propyl]-carbamic acid benzyl ester 

Relevant articles and documents

Carbonyldiimidazole (CDI) mediated synthesis of Nα- protected amino acid azides: Application to the one-pot preparation of ureidopeptides

Synthesis of Nα-protected amino acyl azides starting from corresponding acids via the carbonyldiimidazole (CDI) activation is described. The protocol is extended for a one-pot preparation of ureido peptides that circumvents the isolation of acy

2(3H)-and 2(5H)-furanones. VIII. Preparation and α nucleophilicity of (S)-γ-isopropyl-α-methyl-β-tetramic acid

An efficient preparation of (S)-γ-isopropyl-α-methyl-β-tetramic acid has been established, and the α nucleophilicity of the acid has been also examined.

Enantioselective and diastereoselective formation of syn-3-hydroxy-4-amino acids (syn-statines) via tetramic acids

Enantiomerically pure pyrrolidine-2,4-diones (tetramic acids) which can be diastereoselectively hydrogenated to syn-statines (4-amino-3-hydroxy-6-methylheptanoic acids) have been prepared by catalytic hydrogenation of 4-(benzyloxycarbonylamino)-3-oxocarboxylic acid esters.