66949-28-8 Usage
Description
(Cyclohexylimino)(triphenyl)-lambda~5~-phosphane is a coordination compound characterized by a cyclohexyl substituent attached to an imino group, which is coordinated to a triphenylphosphine ligand. (cyclohexylimino)(triphenyl)-lambda~5~-phosphane is known for its unique structural and electronic properties, making it a valuable tool in the fields of coordination chemistry and organometallic chemistry.
Uses
Used in Coordination Chemistry:
(Cyclohexylimino)(triphenyl)-lambda~5~-phosphane is used as a ligand for forming coordination complexes with transition metal ions. Its ability to act as a bridging ligand allows for the study of metal-ligand interactions and the development of new catalytic processes.
Used in Organometallic Chemistry:
In organometallic chemistry, (cyclohexylimino)(triphenyl)-lambda~5~-phosphane is utilized as a ligand to create organometallic complexes. These complexes have potential applications in various chemical reactions and processes.
Used in Catalysis:
(cyclohexylimino)(triphenyl)-lambda~5~-phosphane is used as a ligand in the synthesis of metal complexes that have potential applications in catalysis. Its unique properties contribute to the enhancement of catalytic activity and selectivity in various chemical reactions.
Used in Materials Science:
(Cyclohexylimino)(triphenyl)-lambda~5~-phosphane is also employed in the synthesis of metal complexes with potential applications in materials science. These complexes can be used to develop new materials with specific properties, such as conductivity, magnetism, or optical properties, depending on the requirements of various industries.
Check Digit Verification of cas no
The CAS Registry Mumber 66949-28-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,6,9,4 and 9 respectively; the second part has 2 digits, 2 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 66949-28:
(7*6)+(6*6)+(5*9)+(4*4)+(3*9)+(2*2)+(1*8)=178
178 % 10 = 8
So 66949-28-8 is a valid CAS Registry Number.
66949-28-8Relevant articles and documents
Bifunctional iminophosphorane organocatalysts for enantioselective synthesis: Application to the ketimine nitro-Mannich reaction
Nunez, Marta G.,Farley, Alistair J. M.,Dixon, Darren J.
supporting information, p. 16348 - 16351 (2013/12/04)
The design, synthesis, and development of a new class of modular, strongly basic, and tunable bifunctional Bronsted base/H-bond-donor organocatalysts are reported. These catalysts incorporate a triaryliminophosphorane as the Bronsted basic moiety and are readily synthesized via a last step Staudinger reaction of a chiral organoazide and a triarylphosphine. Their application to the first general enantioselective organocatalytic nitro-Mannich reaction of nitromethane to unactivated ketone-derived imines allows the enantioselective construction of β-nitroamines possessing a fully substituted carbon atom. The reaction is amenable to multigram scale-up, and the products are useful for the synthesis of enantiopure 1,2-diamine and α-amino acid derivatives.
REDUCTION D'AZIDES EN AMINES PRIMAIRES PAR UNE METHODE GENERALE UTILISANT LA REACTION DE STAUDINGER.
Vaultier, M.,Knouzi, N.,Carrie, R.
, p. 763 - 764 (2007/10/02)
A general chemoselective method for the reduction of azides into primary amines is described.
