66952-06-5

Basic information

• Product Name: diphenylphosphinic hexanoic anhydride
• Synonyms: diphenylphosphinic hexanoic anhydride
• CAS NO: 66952-06-5
• Molecular Weight: 316.337
• Mol File: 66952-06-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diphenylphosphinic hexanoic anhydride(CAS DataBase Reference)
• NIST Chemistry Reference: diphenylphosphinic hexanoic anhydride(66952-06-5)
• EPA Substance Registry System: diphenylphosphinic hexanoic anhydride(66952-06-5)

Safety Data

• Hazardous Substances Data: 66952-06-5(Hazardous Substances Data)

Upstream product

• 142-62-1 hexanoic acid 
• 1499-21-4 Diphenylphosphinic chloride 

Downstream Products

• 5340-64-7 2,2-dimethyl-octan-3-one 
• 4485-09-0 nonan-4-one 

Relevant articles and documents

Phosphorylation with N-Phosphorylpyrazoles, IV. - Phosphorylations of Carboxylic Acids

Reaction of 1-phosphorylpyrazole (1a) with the carboxylic acids 5a-f leads initially to the mixed anhydrides 6a-f, which then transform the 1-H-pyrazole 3, arising from phosphoryl group transfer, into the 1-acylpyrazoles 7a-f.Carboxylic acid phosphinic acid anhydrides 6b, c and g-k are also formed on reaction of the phosphinic acid chloride 9 and carboxylic acids in the presence of triethylamine; acylation of 3 with 6b, c, i and k is described.