66985-46-4Relevant articles and documents
Copper(II) complexes with carboxylic- or sulfonic-functionalized arylhydrazones of acetoacetanilide and their application in cyanosilylation of aldehydes
Gurbanov, Atash V.,Mahmudov, Kamran T.,Sutradhar, Manas,Guedes da Silva, Fátima C.,Mahmudov, Talib A.,Guseinov, Firudin I.,Zubkov, Fedor I.,Maharramov, Abel M.,Pombeiro, Armando J.L.
, p. 22 - 27 (2017)
The new copper(II) complexes [Cu(HL1)(H2O)(CH3OH)] (1, H3L1?= (Z)-2-(2-(1,3-dioxo-1-(phenylamino)butan-2-ylidene)hydrazinyl)benzoic acid) and [Cu(HL2)(H2O)(CH3OH)] (2,
Trinuclear and polymeric cobalt(II or II/III) complexes with an arylhydrazone of acetoacetanilide and their application in cyanosilylation of aldehydes
Gurbanov, Atash V.,Maharramov, Abel M.,Guedes da Silva, M. Fátima C.,Pombeiro, Armando J.L.
, p. 632 - 637 (2017)
The new trinuclear [CoII(H2O)2(Me2NCHO)2{CoIII(1κNOO′:2κO″-μ-HL)}2(1κNOO′)]·2H2O (1) and polymeric [CoII(1κNOO′:2κO″-μ-HL)(MeOH)2]n (2
Packing polymorphism in 3-amino-2-pyrazinecarboxylate based tin(ii) complexes and their catalytic activity towards cyanosilylation of aldehydes
Karmakar, Anirban,Hazra, Susanta,Rúbio, Guilherme M. D. M.,Guedes Da Silva, M. Fátima C.,Pombeiro, Armando J. L.
, p. 17513 - 17523 (2018)
Reactions of 3-amino-2-pyrazinecarboxylic acid (HL) with SnCl2 under different hydrothermal conditions and crystallization processes produced two new mononuclear Sn(ii) compounds (1 and 2) of general formula [Sn(κN,O-L)2] (L = 3-amin
Synthesis, crystal structure and catalytic property of a cadmium(II) coordination polymer derived from a zwitterionic carboxylate ligand
Zhang, Jian-Wei,Cheng, Yan,Liu, Shu-Hua
, p. 347 - 351 (2018)
A new Cadmium(II) zwitterionic coordination polymer, {[Cd(cbdcp)(H2O)4]·H2O}n, (1) was synthesized based on the 1-(3,5-dicarboxybenzyl)-4,4′-bipyridinium bromide (H3cbdcpBr) organic linker. In 1, Cd(I
Two Gd(III) coordination polymers based on a flexible tricarboxylate: Syntheses, structures, luminescence and catalytic properties
Zhu, Yu,Zhu, Min,Liu, Pan,Xia, Li,Wu, Yunlong,Xie, Jimin
, p. 26 - 32 (2017)
Two Gadolinium coordination polymers {[Gd·(TTTA)·(H2O)2]·2H2O}n (1) and [Gd·(TTTA)·DMF]n (2) have been synthesized based on Gd(NO3)3·6H2O and the flexible tripodal lig
Role of metal center and coordination environment in M-(Z)-N-((E)-pyridin-2-ylmethylene)isonicotinohydrazonate (M = LaIII, ZnII, CdII or HgII) catalyzed cyanosilylation of aldehydes
Hajiyeva, Sevinc R.,Huseynov, Fatali E.,Kopylovich, Maximilian N.,Mahmoudi, Ghodrat,Nikitina, Eugeniya V.,Prisyazhnyuk, Ekaterina D.,Shamilov, Nazim T.,Zubkov, Fedor I.
, (2021/09/07)
A series of known metal complexes, [LaL2(NO3)(H2O)2]·5H2O (1), [Zn(μ-L)(NO3)(H2O)]n (2), {[Cd2(μ-HL)(μ-L)(NO3)3(H2O)]·Hsub
Application of an Electrochemical Microflow Reactor for Cyanosilylation: Machine Learning-Assisted Exploration of Suitable Reaction Conditions for Semi-Large-Scale Synthesis
Sato, Eisuke,Fujii, Mayu,Tanaka, Hiroki,Mitsudo, Koichi,Kondo, Masaru,Takizawa, Shinobu,Sasai, Hiroaki,Washio, Takeshi,Ishikawa, Kazunori,Suga, Seiji
supporting information, p. 16035 - 16044 (2021/09/02)
Cyanosilylation of carbonyl compounds provides protected cyanohydrins, which can be converted into many kinds of compounds such as amino alcohols, amides, esters, and carboxylic acids. In particular, the use of trimethylsilyl cyanide as the sole carbon source can avoid the need for more toxic inorganic cyanides. In this paper, we describe an electrochemically initiated cyanosilylation of carbonyl compounds and its application to a microflow reactor. Furthermore, to identify suitable reaction conditions, which reflect considerations beyond simply a high yield, we demonstrate machine learning-assisted optimization. Machine learning can be used to adjust the current and flow rate at the same time and identify the conditions needed to achieve the best productivity.
