6714-00-7

Basic information

• Product Name: hept-5-en-2-one
• Synonyms: hept-5-en-2-one;5-Hepten-2-one
• CAS NO: 6714-00-7
• Molecular Formula: C₇H₁₂O
• Molecular Weight: 112.16958
• EINECS: 229-768-7
• Mol File: 6714-00-7.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 151.3°C at 760 mmHg
• Flash Point: 40.7°C
• Appearance: /
• Density: 0.832g/cm³
• Vapor Pressure: 3.69mmHg at 25°C
• Refractive Index: 1.426
• CAS DataBase Reference: hept-5-en-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: hept-5-en-2-one(6714-00-7)
• EPA Substance Registry System: hept-5-en-2-one(6714-00-7)

Safety Data

• Hazardous Substances Data: 6714-00-7(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 71, p. 3165, 1949 DOI: 10.1021/ja01177a065Tetrahedron Letters, 21, p. 3199, 1980 DOI: 10.1016/S0040-4039(00)77444-2

InChI:InChI=1/C7H12O/c1-3-4-5-6-7(2)8/h3-4H,5-6H2,1-2H3/b4-3+

Upstream product

• 101-84-8 diphenylether 
• 25456-01-3 1-methylprop-2-enyl 3-oxobutanoate 
• 3916-64-1 hepta-3,5-dien-2-one 
• 4784-77-4 (E/Z)-crotyl bromide 
• 6407-36-9 N-isopropyliden-cyclohexyl amine 
• 29149-74-4 2-acetyl-hex-4-enoic acid ethyl ester 
• 108-24-7 acetic anhydride 
• 97675-09-7 pent-3-enylmagnesium bromide 
• 141-97-9 ethyl acetoacetate 
• 591-97-9 1-chloro-2-butene 
• 67-64-1 acetone 
• 4894-61-5 trans-but-2-enyl chloride 
• 123-54-6 acetylacetone 

Downstream Products

• 123-76-2 levulinic acid 
• 110-43-0 n-pentyl methyl ketone 
• 52390-72-4 2-Heptanol 
• 13311-76-7 5-Hepten-2-ol 
• 626-96-0 4-oxopentanal 
• 75-07-0 acetaldehyde 
• 813-19-4 bis(tri-n-butyltin) 
• 99080-64-5 2--hept-5-en 

Relevant articles and documents

Asymmetric synthesis of a highly functionalized bicyclo[3.2.2]nonene derivative

The stereoselective Diels-Alder reaction between an optically active 1,4-dimethylcycloheptadiene and acrolein was effectively promoted by TBSOTf to produce a bicyclo[3.2.2]nonene derivative bearing two quaternary carbons. Seven additional transformations from the obtained bicycle delivered the C 2-symmetric bicyclo[3.3.2]decene derivative, a key intermediate in our synthetic study of ryanodine.

SUBSTITUENT-DIRECTED OXIDATIVE CYCLIZATION OF γ-HYDROXY OLEFINS TO γ-LACTONES WITH HEXAVALENT OXO-CHROMIUM REAGENTS

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