67210-34-8

Basic information

• Product Name: (S)-(-)-(2-hydroxy-2-phenyl-1-ethyl)-phenyl thioether
• CAS NO: 67210-34-8
• Molecular Weight: 230.331
• Mol File: 67210-34-8.mol
• Article Data: 74

Chemical Properties

• CAS DataBase Reference: (S)-(-)-(2-hydroxy-2-phenyl-1-ethyl)-phenyl thioether(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(-)-(2-hydroxy-2-phenyl-1-ethyl)-phenyl thioether(67210-34-8)
• EPA Substance Registry System: (S)-(-)-(2-hydroxy-2-phenyl-1-ethyl)-phenyl thioether(67210-34-8)

Safety Data

• Hazardous Substances Data: 67210-34-8(Hazardous Substances Data)

Upstream product

• 16222-10-9 1-phenyl-2-(phenylthio)ethanone 
• 96-09-3 styrene oxide 
• 108-98-5 thiophenol 
• 100-42-5 styrene 
• 4551-15-9 phenylthiotrimethylsilane 
• 882-33-7 diphenyldisulfane 
• 592-41-6 1-hexene 
• 7205-91-6 phenylthiomethyl chloride 
• 15082-42-5 lithium benzyloxide 
• 49639-26-1 erythro-2-(phenylsulfinyl)-1-phenyl-1-ethanol 
• 100-52-7 benzaldehyde 
• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 
• 754-05-2 ethenyltrimethylsilane 
• 16619-61-7 1-phenyl-2-phenylthioethene 

Downstream Products

• 141341-45-9 (2-methoxy-2-phenylethyl)(phenyl)sulfane 
• 93570-58-2 1-(Hydroxy-2-phenylethyl)cyclohexanol 
• 16162-51-9 (S)-(-)-(2-hydroxy-2-phenyl-1-ethyl)-phenyl thioether 
• 1445-91-6 (S)-1-phenylethanol 
• 1517-69-7 (R)-1-phenylethanol 
• 100-68-5 methyl-phenyl-thioether 
• 100-52-7 benzaldehyde 
• 79157-37-2 1-phenyl-1-(3,4-dimethoxyphenyl)ethylene 
• 51003-88-4 1-(3,4-methylendioxyphenyl)-1-(phenyl)ethene 
• 24890-52-6 1-phenyl-1-(2,4-dimethoxyphenyl)ethylene 

Relevant articles and documents

Solvent-mediated switching between oxidative addition and addition-oxidation: Access to β-hydroxysulfides and β-arylsulfones by the addition of thiols to olefins in the presence of Oxone

The reaction between aryl olefins and thiols in the presence of Oxone in toluene-water (9:1, v/v) affords β-hydroxy-2-arylethyl aryl sulfides smoothly by the interception of intermediary thiyl radicals with aryl olefins; the former are generated by the ox

Competition Between Cα-S and Cα-Cβ Bond Cleavage in β-Hydroxysulfoxides Cation Radicals Generated by Photoinduced Electron Transfer?

A kinetic and product study of the 3-cyano-N-methyl-quinolinium photoinduced monoelectronic oxidation of a series of β-hydroxysulfoxides has been carried out to investigate the competition between Cα-S and Cα-Cβ bond cleavage within the corresponding cation radicals. Laser flash photolysis experiments unequivocally established the formation of sulfoxide cation radicals showing their absorption band (λmax ≈ 520?nm) and that of 3-CN-NMQ? (λmax ≈ 390?nm). Steady-state photolysis experiments suggest that, in contrast to what previously observed for alkyl phenyl sulfoxide cation radicals that exclusively undergo Cα-S bond cleavage, the presence of a β-hydroxy group makes, in some cases, the Cα-Cβ scission competitive. The factors governing this competition seem to depend on the relative stability of the fragments formed from the two bond scissions. Substitution of the β-OH group with -OMe did not dramatically change the reactivity pattern of the cation radicals thus suggesting that the observed favorable effect of the hydroxy group on the Cα-Cβ bond cleavage mainly resides on its capability to stabilize the carbocation formed upon this scission.

Air-Induced Disulfenylation of Alkenes: Facile Synthesis of Vicinal Dithioethers

A novel disulfenylation of alkenes with thiophenols and their corresponding disulfides by using air as the oxidant has been achieved. This transformation provides a facile and practical protocol for the synthesis of vicinal dithioethers under mild conditions.