67245-14-1Relevant articles and documents
Synthesis of a comprehensive polyprenol library for the evaluation of bacterial enzyme lipid substrate specificity
Wu, Baolin,Woodward, Robert,Wen, Liuqing,Wang, Xuan,Zhao, Guohui,Wang, Peng George
, p. 8162 - 8173 (2014/01/06)
Polyprenols, a universal class of glycan-carrier lipids, play important roles in glycan biosynthesis in wide variety of living organisms. The chemical synthesis of natural polyisoprenols such as undecaprenol and dolichols, and even more so the synthesis o
Cyclopropenation of alkylidene carbenes derived from α-silyl ketones
Li, Jingwei,Sun, Chunrui,Lee, Daesung
supporting information; experimental part, p. 6640 - 6641 (2010/07/04)
A new cyclopropanation reaction involving Cα-Si bond insertion of alkylidene carbenes derived from α-silyl ketones has been developed. This unprecedented alkylidene carbene reactivity features excellent selectivity for insertion into Cα-Si bonds rather than insertion into Cγ-H bonds or addition to,δ-double or -triple bonds. The selectivity trend clearly indicates that the α-oxygen in the tether significantly promotes Cγ-H insertion, although the Cα-Si bond insertion still competes effectively.
A SIMPLE AND EFFICIENT SYNTHESIS OF 3-METHYL-6-(1-METHYLETHENYL)-9-DECEN-1-YL ACETATE A COMPONENT OF THE CALIFORNIA RED SCALE PHEROMONE
Calo, Vincenzo,Lopez, Luigi,Fiandanese, Vito
, p. 577 - 579 (2007/10/02)
A diastereomeric mixture of (3S,6R) and (3S,6S) 3-methyl-6-(1-methylethenyl)-9-decen-1-yl acetate 1(a,b) has been synthesized in high yield starting from (S)-(-)-citronellol.The key step of the synthesis is the regioselective coupling of the benzothiazole
