67251-60-9

Basic information

• Product Name: (η-C5H5)Mo(CO)3(PPh3)BF4
• Synonyms: (η-C5H5)Mo(CO)3(PPh3)BF4
• CAS NO: 67251-60-9
• Molecular Weight: 594.161
• Mol File: 67251-60-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (η-C5H5)Mo(CO)3(PPh3)BF4(CAS DataBase Reference)
• NIST Chemistry Reference: (η-C5H5)Mo(CO)3(PPh3)BF4(67251-60-9)
• EPA Substance Registry System: (η-C5H5)Mo(CO)3(PPh3)BF4(67251-60-9)

Safety Data

• Hazardous Substances Data: 67251-60-9(Hazardous Substances Data)

Upstream product

• 80823-53-6 [(C₅H₅)(CO)2(P(C₆H₅)3)Mo]⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)(CO)2(P(C₆H₅)3)Mo]BF₄ 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 536-74-3 phenylacetylene 
• 74-86-2 acetylene 
• 78833-68-8 (C₅H₅)Mo(CO)2((C₆H₅)3P)2⁽¹⁺⁾*BF₄^(1-)={(C₅H₅)Mo(CO)2((C₆H₅)3P)2}{BF₄} 
• 14104-20-2 silver tetrafluoroborate 
• 12176-06-6 hydrido(tricarbonyl)(cyclopentadienyl)molybdenum 
• 341-02-6 trityl tetrafluoroborate 
• 501-65-5 diphenyl acetylene 

Downstream Products

• 78090-78-5 {cyclopentadienyl(CO)Mo(PPh₃)PhCCPh}BF₄ 
• 88642-96-0 trans-(η-C5H5)Mo(CO)2(PPh3)CHO 
• 78110-74-4 {cycopentadienyl(CO)Mo(PPh₃)MeCCMe}BF₄ 
• 78833-68-8 (C₅H₅)Mo(CO)2((C₆H₅)3P)2⁽¹⁺⁾*BF₄^(1-)={(C₅H₅)Mo(CO)2((C₆H₅)3P)2}{BF₄} 

Relevant articles and documents

Synthesis and thermolysis of neutral metal formyl complexes of molybdenum, tungsten, manganese, and rhenium

The possible intermediacy of catalyst-bound formyls in syngas transformations has prompted efforts to prepare and study the chemistry of transition-metal formyl complexes over more than a decade. We have used a mild borohydride in our reactions with metal carbonyl cations and have introduced some variations into the syntheses which allow, in almost all cases, for the pure formyl complex to be precipitated from solution as it is formed. The formyl complexes and their cationic precursors are shown. Seven of the formyls are new; improved procedures have been established for the other four. All but one of the compounds have been isolated.

METALLORGANISCHE LEWIS-SAEUREN; METALLKOMPLEXE MIT SCHWACH KOORDINIERTEN LIGANDEN. VIII. REAKTIONEN VON TETRAFLUOROBORATO-KOMPLEXEN (η5-C5H5)(CO)2(L)(MoFBF3 (L = CO, PR3) MIT ALKINEN

The reaction of the tetrafluoroborato compounds (η5-C5H5)(CO)2(L)MoFBF3 with various alkynes gives mono- and bis-alkyne complexes 5-C5H5)Mo(CO)(RCCR')2>+ BF4- (III) and 5-C5H5)Mo(CO)(L)(RCCR')>