67279-09-8

Basic information

• Product Name: 1-O-acetyl-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-xylo-hexopyranose
• Synonyms: 1-O-acetyl-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-xylo-hexopyranose
• CAS NO: 67279-09-8
• Molecular Weight: 434.326
• Mol File: 67279-09-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-O-acetyl-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-xylo-hexopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1-O-acetyl-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-xylo-hexopyranose(67279-09-8)
• EPA Substance Registry System: 1-O-acetyl-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-xylo-hexopyranose(67279-09-8)

Safety Data

• Hazardous Substances Data: 67279-09-8(Hazardous Substances Data)

Upstream product

• 122-04-3 4-nitro-benzoyl chloride 
• 76753-24-7 methyl-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-L-xylo-hexopyranoside 
• 72002-53-0 methyl-2,3,6-tridesoxy-3-trifluoroacetamido-β-L-xylo-hexopyranoside 
• 67737-60-4 methyl-3-amino-2,3,6-tridesoxy-β-L-xylo-hexopyranoside 
• 108-24-7 acetic anhydride 
• 76753-25-8 2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α,β-L-xylo-hexopyranose 

Downstream Products

• 76793-42-5 7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-xylo-hexopyranosyl)daunomycinone 

Relevant articles and documents

HEMISYNTHESE DE NOUVEAUX GLICOSIDES ANALOGUES DE LA DAUNORUBICINE

Seven daunorubicin analogs containing α-L-, α-D-, and β-D-glicosidic linkages, in which the natural occuring sugar (L-daunosamine) was replaced by diastereomeric 3-amino-2,3,6-trideoxyhexoses (3-epi-L-daunosamine, D-acosamine, D-daunosamine, D-ristosamine, and 3-epi-D-daunosamine), were prepared.In all cases, glycosidation with daunomycinone was performed in the presence of p-toluenesulfonic acid starting from 1-O-acetyl-2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoro-acetamidohexopyranoses (prepared from the corresponding methyl 3-amino-2,3,6-trideoxyhexopyranosides) or from 1,5-anhydro-2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamidohex-1-enitols (prepared from glycosals or pseudoglycals, the 3-amino group being introduced by substitution with sodium azide and subsequent reduction).Glycosidation was followed by removal of the protecting groups.