673-97-2Relevant articles and documents
Catalytic degradation of the nerve agent vx by water-swelled polystyrene-supported ammonium fluorides
Marciano, Daniele,Goldvaser, Michael,Columbus, Ishay,Zafrani, Yossi
scheme or table, p. 8549 - 8553 (2011/12/04)
The catalytic degradation of the nerve agent VX (O-ethyl S-2-(diisopropylamino)ethyl methylphosphonothioate) by water-swelled polymer-supported ammonium fluorides is described. VX (0.06-0.53 mol/mol F -) is rapidly degraded (t1/2 ~ 10-30 min) to form the G-analogue (O-ethyl methylphosphonofluoridate), which hydrolyzes (t 1/2 ~ 1-1.5 h) to the nontoxic EMPA (ethyl methylphosphonic acid). The toxic desethyl-VX is not formed. The catalytic effect of fluoride is maintained even when 6 equiv of VX are loaded. GB (O-isopropyl methylphosphonofluoridate) and desethyl-VX agents are also degraded under these conditions.
The Use of Organosilicon Esters for the Synthesis of Alkyl Phosphonofluoridates
Muller, August J.
, p. 3364 - 3365 (2007/10/02)
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