67363-83-1

Basic information

• Product Name: 2-Naphthalenamine, 6-methyl-N-phenyl-
• CAS NO: 67363-83-1
• Molecular Formula: C17H15N
• Molecular Weight: 233.313
• Mol File: 67363-83-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Naphthalenamine, 6-methyl-N-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Naphthalenamine, 6-methyl-N-phenyl-(67363-83-1)
• EPA Substance Registry System: 2-Naphthalenamine, 6-methyl-N-phenyl-(67363-83-1)

Safety Data

• Hazardous Substances Data: 67363-83-1(Hazardous Substances Data)

Upstream product

• 17579-79-2 2-methyl-6-hydroxynaphthalene 
• 62-53-3 aniline 
• 13035-04-6 sodium 6-methyl-2-naphthalene sulfonate 

Relevant articles and documents

Nickel-Catalyzed Kumada Coupling of Boc-Activated Aromatic Amines via Nondirected Selective Aryl C-N Bond Cleavage

A nickel-catalyzed Kumada coupling of aniline derivatives was developed by selective cleavage of aryl C-N bonds under mild reaction conditions. Without preinstallation of an ortho directing group on anilines, the cross-coupling reactions of Boc-protected aromatic amines with aryl Grignard reagents afforded unsymmetric biaryls. Mechanistic studies by DFT calculations revealed that the nickel-mediated C-N bond cleavage is the rate-limiting step.

REACTION OF SODIUM SALTS OF AROMATIC SULFONIC ACIDS WITH ALKALI-METAL ARYLIDES

In the reaction of the sodium salts of benzenesulfonic acid, 1-naphthalenesulfonic acid, and 2-methyl-6-naphthalenesulfonic acid with alkali-metal arylides the sulfo groups are substituted by arylamino groups, and diphenylamine, N-phenyl-1-naphthylamine, N-(p-tolyl)-2-naphthylamine, 2-methyl-N-phenyl-6-naphthylamine, and dinaphthylamine are formed.In the reaction of disodium salts of aromatic disulfonic acids with sodium anilide substitution of the sulfo groups by arylamino groups gave N,N'-diphenyl-m-phenylenediamine, N,N'-diphenyl-p-phenylenediamine, and N,N'-diphenyl-2,6-naphthylenediamine.