67470-03-5Relevant articles and documents
REGIO-CONTROLLED FUNCTIONALIZATION OF 2,5-DIMETHYL-2,4-HEXADIENE INTO EPOXY ALCOHOLS BY PHOTOOXYGENATION IN THE PRESENCE OF TITANIUM(IV) OR VANADIUM(V)
Adam, Waldemar,Staab, Eugen
, p. 531 - 534 (2007/10/02)
Using Ti(OiPr)4 as oxygen transfer catalyst, the diene 1 afforded exclusively the epoxy alcohol 1c, but VO(acac)2 gave exclusively the isomerized epoxy alcohol 2c during its ene reaction with singlet oxygen.