67628-16-4Relevant articles and documents
Umpolung of Imines Enables Catalytic Asymmetric Regio-reversed [3+2] Cycloadditions of Iminoesters with Nitroolefins
Feng, Bin,Lu, Liang-Qiu,Chen, Jia-Rong,Feng, Guoqiang,He, Bin-Qing,Lu, Bin,Xiao, Wen-Jing
supporting information, p. 5888 - 5892 (2018/05/14)
A copper-catalyzed regio-reversed asymmetric [3+2] cycloaddition of iminoesters with nitroolefins is disclosed for the first time. This method enables the facile synthesis of polysubstituted chiral pyrrolidines bearing at least one chiral quaternary cente
X=Y-ZH Systems as Potential 1,3-Dipoles. Part 8. Pyrrolidines and Δ5-Pyrrolines (3,7-Diazabicyclooctenes) from the Reaction of Imines of α-Amino Acids and their Esters with Cyclic Dipolarophiles. Mechanism of Racemisation of α-Amino Acid
Amornraksa, Kitti,Grigg, Ronald,Gunaratne, H. Q. Nimal,Kemp, James,Sridharan, Visuvanathar
, p. 2285 - 2296 (2007/10/02)
Imines of α-amino acid esters with aromatic, heterocyclic, and aliphatic aldehydes generate azomethine ylides stereospecifically by a prototropic shift on heating in toluene.The azomethine ylides undergo cycloaddition to N-phenylmaleimide, maleic anhydrid
