676591-83-6Relevant articles and documents
Synthesis of disubstituted ynamides from β,β-dichloroenamides and electrophiles
Rodríguez, David,Martínez-Esperón, M. Fernanda,Castedo, Luis,Saá, Carlos
, p. 1963 - 1965 (2007)
Treatment of β,β-dichloroenamides with n-butyllithium, followed by addition of an electrophile, provides disubstituted ynamides in far greater yield than direct functionalization of terminal ynamides. Georg Thieme Verlag Stuttgart.
Intermolecular and selective synthesis of 2,4,5-trisubstituted oxazoles by a gold-catalyzed formal [3+2] cycloaddition
Davies, Paul W.,Cremonesi, Alex,Dumitrescu, Lidia
supporting information; experimental part, p. 8931 - 8935 (2011/10/19)
Oxazole new world: A gold-catalyzed intermolecular reaction of pyridine-N-aminides with ynamides can be used to prepare trisubstituted 1,3-oxazoles with a variety of functional groups. This formal [3+2] cycloaddition employs robust conjugated N-ylides as
Homocoupling of 1-Alkynyl Tosylamides
Rodri?guez, David,Castedo, Luis,Saa?, Carlos
, p. 377 - 379 (2007/10/03)
N,N′-substituted-buta-1,3-diyne-1,4-tosylamides have been synthesized for the first time, in good to excellent yields, via copper-catalyzed dimerization of the corresponding 1-alkynyltosylamides.