677007-65-7Relevant articles and documents
Diastereo- and Enantioselective Catalytic Radical Oxysulfonylation of Alkenes in β,γ-Unsaturated Ketoximes
Cheng, Gui-Juan,Gu, Qiang-Shuai,Li, Xi-Tao,Li, Zhong-Liang,Liu, Xin-Yuan,Lv, Ling,Wang, Ting,Xu, Guo-Xing,Ye, Liu,Zhang, Xinhao
supporting information, p. 1692 - 1706 (2020/07/08)
The asymmetric radical-initiated difunctionalization of internal alkenes, which creates two vicinal stereocenters, has been a significant synthetic challenge despite the tremendous progress achieved for terminal alkenes. This is attributable to the common
Biomimetic hydrogenation: A reusable NADH co-enzyme model for hydrogenation of α,β-epoxy ketones and 1,2-diketones
Huang, Qiang,Wu, Ji-Wei,Xu, Hua-Jian
supporting information, p. 3877 - 3881 (2013/07/05)
A biomimetic method has been developed to transform α,β-epoxy ketones or 1,2-diketones into corresponding β-hydroxy ketones or α-hydroxy ketones using a catalytic amount of BNAH or BNA +Br-. The regeneration of BNAH or BNA+Br - is achieved by a mixture of HCOOH/Et3N. A radical mechanism is proposed to explain these observations.
