6781-96-0

Basic information

• Product Name: dichloro(mesityl)phosphane
• Synonyms: dichloro(mesityl)phosphane
• CAS NO: 6781-96-0
• Molecular Weight: 221.066
• Mol File: 6781-96-0.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: dichloro(mesityl)phosphane(CAS DataBase Reference)
• NIST Chemistry Reference: dichloro(mesityl)phosphane(6781-96-0)
• EPA Substance Registry System: dichloro(mesityl)phosphane(6781-96-0)

Safety Data

• Hazardous Substances Data: 6781-96-0(Hazardous Substances Data)

Upstream product

• 576-83-0 2,4,6-trimethylphenyl bromide 
• 5806-59-7 mesityllithium 
• 2633-66-1 2-mesitylmagnesium bromide 
• 108-67-8 1,3,5-trimethyl-benzene 
• 116005-25-5 bis(dimethylamino)mesitylphosphine 
• 99107-86-5 dimesitylmagnesium 

Downstream Products

• 137787-47-4 1-Mesityl 2,3-dimethylphosphirene 
• 28036-01-3 diethyl [(2’,4’,6’-trimethyl)phenyl]phosphonate 
• 918148-11-5 dimethyl-[2-(2,4,6-trimethyl-phenylphosphanyl)-benzyl]-amine 
• 68357-98-2 mesitylphosphine 
• 1515803-47-0 C₂₅H₂₉P 
• 1515803-55-0 C₃₁H₂₂BF₁₀P 
• 1515803-45-8 C₁₉H₂₁P 

Relevant articles and documents

Transition-Metal Carbonyl Complexes and Electron-Donating Properties of N-Heterocyclic-Carbene–Phosphinidene Adducts

Rhodium(I), tungsten(0), and molybdenum(0) carbonyl complexes of the N-heterocyclic-carbene–phosphinidene adducts IPr·PR [1a, R = H; 1b, R = Ph; 1c, R = Mes; IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene; Mes = 2,4,6-trimethylphenyl] were prepa

Chromium-Catalyzed Highly Selective Oligomerization of Ethene to 1-Hexene with N,N-Bis[chloro(aryl)phosphino]amine Ligands

Different N,N-bis[chloro(aryl)phosphino]amines were synthesized and characterized. The synthesized compounds were tested as ligands in the Cr-catalyzed oligomerization of ethene. The effect of the successive increase of the steric bulk either at one of th

Ring-Opening Polymerization of Cyclic Phosphonates: Access to Inorganic Polymers with a PV-O Main Chain

We describe a new class of inorganic polymeric materials featuring a main chain consisting of PV-O bonds and aryl side groups, which was obtained with >70 repeat units by ring-opening polymerization of cyclic phosphonates. This monomer-polymer system was found to be dynamic in solution enabling selective depolymerization under dilute conditions, which can be tuned by varying the substituents. The polymers show high thermal stability to weight loss and can be easily fabricated into self-standing thin films. Structural characterizations of the cyclic 6-and 12-membered ring precursors are also described.

A hydroboration route to geminal P/B frustrated Lewis pairs with a bulky secondary phosphane component and their reaction with carbon dioxide

The secondary aryl-P(H) phosphanyl substituted tert-butylacetylenes 7a,b (aryl: Mes or Mes?) undergo hydroboration with [HB(C6F5)2] to give the geminal vinylidene-bridged P/B Lewis pairs 8a,b. The treatment of 8a,b with benzonitrile, N-sulfinylaniline, and phenyl isothiocyanate, respectively, gives the addition products 12a,b, 13a,b, and 14 with proton transfer from the phosphorus to the more basic nitrogen site. The reaction of the FLPs 8a,b with carbon dioxide yields a doubly boron bonded addition product. The reaction of 8b with a conjugated ynone formally proceeded by trans-1,2-hydrophosphination of the alkyne at the geminal FLP framework to give the seven-membered heterocycle 21.