67886-01-5

Basic information

• Product Name: 6-(phenylsulfonyl)-2-hexanone
• Synonyms: 6-(phenylsulfonyl)-2-hexanone
• CAS NO: 67886-01-5
• Molecular Weight: 240.323
• Mol File: 67886-01-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-(phenylsulfonyl)-2-hexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 6-(phenylsulfonyl)-2-hexanone(67886-01-5)
• EPA Substance Registry System: 6-(phenylsulfonyl)-2-hexanone(67886-01-5)

Safety Data

• Hazardous Substances Data: 67886-01-5(Hazardous Substances Data)

Upstream product

• 67886-02-6 1-Phenylsulfonyl-5-hexanol 
• 10226-29-6 6-Bromo-2-hexanone 
• 873-55-2 sodium benzenesulfonate 
• 88526-08-3 (S)-(+)-6-(phenylsulfonyl)-2-hexanol 
• 67-68-5 dimethyl sulfoxide 

Downstream Products

• 67886-03-7 (1R,2R,4S)-2-(2-Benzenesulfonyl-6-benzyloxy-heptanoyl)-4-hydroxy-cyclopentanecarboxylic acid 
• 67886-00-4 5-Benzyloxyhexylphenylsulfon 
• 99837-77-1 (S)-(+)-6-(phenylsulfonyl)-2-hexyl (methylthio)methyl ether 
• 67886-02-6 1-Phenylsulfonyl-5-hexanol 
• 88526-08-3 (S)-(+)-6-(phenylsulfonyl)-2-hexanol 

Relevant articles and documents

Secondary Phosphine Oxides as Multitalented Preligands En Route to the Chemoselective Palladium-Catalyzed Oxidation of Alcohols

Secondary phosphine oxides O=PHR2 (SPOs) were identified as multitalented preligands for the chemoselective Pd-catalyzed oxidation of alcohols by a hydrogen-abstracting methodology. SPOs were found to promote the hydrogen-abstraction step as well as hydrogen transfer to a Michael acceptor by generating a putative active H?Pd species. The catalytic system operates under neutral conditions and was proven to be compatible with various electrophilic and nucleophilic functionalities within the substrates as well as water- and air-sensitive functional groups.