679390-77-3Relevant articles and documents
Synthesis of 1,1-diarylethylenes from an α-stannyl β-silylstyrene
Belema, Makonen,Nguyen, Van N.,Zusi, F. Christopher
, p. 1693 - 1697 (2007/10/03)
The synthesis of a family of 1,1-diarylethylenes from an α-stannyl β-silylstyrene through a combination of a Stille coupling and a protodesilylation reaction is described. This approach avoids the problematic cine-substitution, which is a well documented side reaction during the palladium-assisted elaboration of α-substituted vinylstannanes to 1,1-disubstituted ethylenes.