68157-27-7

Basic information

• Product Name: adamantan-2-yl(phenyl)methanone
• Synonyms: adamantan-2-yl(phenyl)methanone
• CAS NO: 68157-27-7
• Molecular Weight: 240.345
• Mol File: 68157-27-7.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: adamantan-2-yl(phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: adamantan-2-yl(phenyl)methanone(68157-27-7)
• EPA Substance Registry System: adamantan-2-yl(phenyl)methanone(68157-27-7)

Safety Data

• Hazardous Substances Data: 68157-27-7(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 6343-27-7 1-benzoylpyrrolidine-2,5-dione 
• 281-23-2 adamantane 
• 7314-85-4 2-adamantyl bromide 
• 15897-81-1 adamantane-2-carboxylic acid 
• 72590-63-7 2-(methoxymethylene)adamantane 
• 39750-93-1 adamantane-2-carbaldehyde 
• 700-58-3 2-Adamantanone 
• 53140-72-0 2-adamantyl(phenyl)methanol 
• 24398-88-7 ethyl 3-bromobenzoate 
• 3277-27-8 diethyl benzoylphosphonate 
• 40079-92-3 2-adamantanecarbonyl chloride 
• 71-43-2 benzene 
• 35856-00-9 2-adamantanecarbonitrile 

Downstream Products

• 113849-79-9 1-(2-Adamantylidene)-1-methoxy-1-phenylmethane 
• 219812-03-0 2-benzoyl-2-methyladamantane 
• 53140-72-0 2-adamantyl(phenyl)methanol 

Relevant articles and documents

ELECTRON-TRANSFER INDUCED CONVERSION OF ENOL-ETHERS INTO KETONES

Alkoxy (aryl)-methylidene adamantanes react with catalytic amounts of tris p-bromophenylammoniumyl hexachloroantimonate in CH2Cl2 under argon atmosphere, yielding adamantyl-arylketones together with the corresponding alcohols.The reaction most likely proc

Adamantylzinc bromides: Direct preparation and application to cross-coupling reaction

-

McMurry intermolecular cross-coupling between an ester and a ketone: Scope and limitations

In the course of our studies towards the synthesis of a dioxetane bearing chemiluminescent probe for the detection of thiols, we were faced with the synthesis of sterically hindered benzylic enol ethers. This issue was solved via the use of an intermolecular McMurry cross-coupling between an ester and a ketone. In this article, together with the synthesis of the chemiluminescent probe, the scope and limitations of this low valent titanium based carbon-carbon double bond formation are discussed.