68253-31-6

Basic information

• Product Name: (2R,3S)-2-Chloro-3-phenylselanyl-tetrahydro-pyran
• CAS NO: 68253-31-6
• Molecular Weight: 275.637
• Mol File: 68253-31-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3S)-2-Chloro-3-phenylselanyl-tetrahydro-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S)-2-Chloro-3-phenylselanyl-tetrahydro-pyran(68253-31-6)
• EPA Substance Registry System: (2R,3S)-2-Chloro-3-phenylselanyl-tetrahydro-pyran(68253-31-6)

Safety Data

• Hazardous Substances Data: 68253-31-6(Hazardous Substances Data)

Upstream product

• 110-87-2 3,4-dihydro-2H-pyran 
• 5707-04-0 Phenylselenyl chloride 

Downstream Products

• 59345-48-1 methyl 2-methyl-2-(phenylselanyl)propanoate 
• 89113-88-2 2-Methyl-2-((2S,3R)-3-phenylselanyl-tetrahydro-pyran-2-yl)-propionic acid methyl ester 
• 89113-86-0 3,3-Dimethyl-1-((2S,3R)-3-phenylselanyl-tetrahydro-pyran-2-yl)-butan-2-one 
• 104755-34-2 3,3-dimethyl-1-phenylselanylbutan-2-one 
• 89113-91-7 2-((2S,3R)-3-Phenylselanyl-tetrahydro-pyran-2-yl)-propionic acid ethyl ester 
• 76893-72-6 Ethyl 2-methyl-2-(phenylseleno)propionate 

Relevant articles and documents

ALKENE CARBOSULPHENYLATION AND CARBOSELENYLATION: THE USE OF ALLYLTRIMETHYLSILANE AND O-SILYLATED ENOLATES.

Allyltrimethylsilane, as well as O-silylated enolates, can be alkylated by the PhSCl adducts of alkenes and vinyl ethers (1, X=SPh); the PhSeCl analogues (1, X=SePh), however, are less useful for alkylation purposes due to competing nucleophilic attack at selenium.